1-(2,4,6-trimethylbenzyl)imidazolinedichloro(dimethylphenylphosphine)palladium(II) | 745784-45-6

• 英文名称: 1-(2,4,6-trimethylbenzyl)imidazolinedichloro(dimethylphenylphosphine)palladium(II)
• CAS: 745784-45-6
• 化学式: C₂₁H₂₉Cl₂N₂PPd
• 分子量: 517.774
• InChiKey: WTMATSNHODMTCK-UHFFFAOYSA-L

计算性质

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反应信息

• 作为产物：
  描述：

  1-(2,4,6-trimethylbenzyl)imidazoline 、 dichlorobis(dimethylphenylphosphine)palladium(II) 以 甲苯 为溶剂， 以81%的产率得到1-(2,4,6-trimethylbenzyl)imidazolinedichloro(dimethylphenylphosphine)palladium(II)
  参考文献：
  名称：

  Synthesis of novel 1-alkylimidazoline and 1-alkylbenzimidazole palladium(II) complexes as efficient catalysts for Heck and Suzuki reactions involving arylchlorides

  摘要：

  Six palladium(II) complexes of the type [PdCl2(PR3)L], {PR3 = PPh3 or PPhMe2; L = 1-alkyl-2-imidazoline(1) or 1-alkylbenzimidazole(2)} have been prepared by reactions of [PdCl2(PR3)](2). The complexes were characterized by conventional spectroscopic methods and elemental analyses. The incorporation of N-coordinated imidazoline and benzimidazole complexes of palladium(II) gave high catalytic activity in the Suzuki coupling and Heck reaction of aryl bromides and deactivated aryl chloride substrates. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2003.07.010