(3ar,7ac)-Hexahydro-indan-2t-ol | 65844-50-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3ar,7ac)-Hexahydro-indan-2t-ol
• 英文别名: (3ar,7ac)-Hexahydro-indan-2t-ol；2α-Hydroxy-cis-hydrindan；cis-cis-β-Hydrindanol-I；cis-cis-β-I-Hydrindanol；cis-β-Hydrindanol-II；cis-β-Hydrindanol
• CAS: 65844-50-0
• 化学式: C₉H₁₆O
• 分子量: 140.225
• InChiKey: FNTAZLZSKBIIIW-BRPSZJMVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.95
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  trans-Hexahydroinden-oxid-(1,2) 在 platinum(IV) oxide 氢气 作用下， 以 乙醇 为溶剂， 生成 (3ar,7ac)-Hexahydro-indan-2t-ol
  参考文献：
  名称：

  Hueckel,W. et al., Justus Liebigs Annalen der Chemie, 1970, vol. 741, p. 1 - 12

  摘要：

  DOI：

文献信息

• Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes
  作者：Christophe J Rousset、Douglas R Swanson、Frédéric Lamaty、Ei-ichi Negishi

  DOI：10.1016/s0040-4039(01)93459-8

  日期：——
• Hueckel et al., Justus Liebigs Annalen der Chemie, 1935, vol. 518, p. 155,173, 175
  作者：Hueckel et al.

  DOI：——

  日期：——
• Hueckel; Friedrich, Justus Liebigs Annalen der Chemie, 1927, vol. 451, p. 159
  作者：Hueckel、Friedrich

  DOI：——

  日期：——
• Hueckel,W. et al., Justus Liebigs Annalen der Chemie, 1961, vol. 645, p. 162 - 176
  作者：Hueckel,W. et al.

  DOI：——

  日期：——
• HETEROGENEOUS CATALYSTS FOR SUBSTRATE-DIRECTED HYDROGENATION AND METHODS OF PRODUCING SUCH CATALYSTS
  申请人：Purdue Research Foundation

  公开号：US20220219150A1

  公开（公告）日：2022-07-14

  A heterogeneous catalyst for substrate-directed hydrogenation includes bimetallic nanoparticles of M 1 -M 2 , wherein M 1 is a noble metal and M 2 is a first-row transition metal. The bimetallic nanoparticles are on a substrate and atoms of both the noble metal and the first-row transition metal are distributed across surfaces of the bimetallic nanoparticles. The heterogeneous catalyst may be produced by providing M 1 -M 2 bimetallic nanoparticles on a substrate to produce an intermediate composition, and performing a reduction process on the intermediate composition such that atoms of both the noble metal (M 1 ) and the first-row transition metal (M 2 ) are distributed across surfaces of the bimetallic nanoparticles and thereby form the heterogeneous catalyst. The catalyst may be used for performing directed hydrogenation of a substrate.