pentyl-4'-hydroxybiphenyl-4-carboxylate | 123790-27-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentyl-4'-hydroxybiphenyl-4-carboxylate
• 英文别名: Pentyl 4-(4-hydroxyphenyl)benzoate
• CAS: 123790-27-2
• 化学式: C₁₈H₂₀O₃
• 分子量: 284.355
• InChiKey: GUDMIVDXTSJGMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  pentyl-4'-hydroxybiphenyl-4-carboxylate 在 4-二甲氨基吡啶 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 二异丙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 76.0h， 生成 pentyl 4'-(4-phenylethynylbenzoyloxy)biphenyl-4-carboxylate
  参考文献：
  名称：

  SYNTHESIS AND PHASE BEHAVIOR OF LIQUID CRYSTALLINE DIPHENYLACETYLENE DERIVATIVES POSSESSING HIGH CLEARING TEMPERATURES

  摘要：

  DOI：

  10.1080/15421400490425784
• 作为产物：
  描述：

  4-乙酰氧基-4'-溴代联苯 在 氢氧化钾 、 溴乙烷 、 氢溴酸 、 氢气 、 potassium carbonate 、 magnesium 作用下， 以 乙醚 、 乙醇 、 溶剂黄146 、 丙酮 、 甲苯 为溶剂， 反应 2.0h， 生成 pentyl-4'-hydroxybiphenyl-4-carboxylate
  参考文献：
  名称：

  Surendranath, V.; Fishel, D. L.; Vries, A de, Molecular Crystals and Liquid Crystals (1969-1991), 1985, vol. 131, p. 1 - 8

  摘要：

  DOI：

文献信息

• Method of producing thermotropic liquid crystalline polyester
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0520428A2

  公开（公告）日：1992-12-30

  A thermotropic liquid crystalline polyester is produced by carrying out polycondensation of ester monomer [I-2], an aromatic dicarboxylic acid [II] and an aromatic carboxylic acid [III-2]. The amounts of the compounds [I-2] and [II] are substantially equivalent and the amount of the compound [III-2] is not more than 20 times that of [I-2] by mole. A thermotropic liquid crystalline polyester having good heat resistance, fluidity and uniformity can be produced.

  通过酯单体[I-2]、芳香族二羧酸[II]和芳香族羧酸[III-2]的缩聚反应，生产出一种热致性液晶聚酯。化合物[I-2]和[II]的量基本相等，化合物[III-2]的量不超过[I-2]的 20 倍（以摩尔计）。这样就可以生产出具有良好耐热性、流动性和均匀性的热致性液晶聚酯。
• High polymer and ferroelectric liquid crystal composition utilizing same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0548808A2

  公开（公告）日：1993-06-30

  A high polymer comprising a recurring unit (I) represented by the formula: and a recurring unit (II) represented by the formula: wherein r, u, p and s each represent an integer of 2 to 5, q represents a number of 0 to 20, m represents an integer of 8 to 12, n represents an integer of 6 to 15, a represents an integer of 1 to 8, b represents an integer of 5 to 15, Y represents -O- or -COO-, Z represents -O-or a single bond, and * represents an asymmetric carbon, and a ferroelectric liquid crystal composition comprising the high polymer and a low molecular weight smectic liquid crystal are disclosed.

  一种高聚物，包含由式(I)代表的递归单元： 式所代表的递归单元（II）： 其中 r、u、p 和 s 分别代表 2 至 5 的整数，q 代表 0 至 20 的数字，m 代表 8 至 12 的整数，n 代表 6 至 15 的整数，a 代表 1 至 8 的整数，b 代表 5 至 15 的整数，Y 代表 -O- 或 -COO-，Z 代表 -O- 或单键，* 代表不对称碳，本发明公开了一种铁电液晶组合物，该组合物包含该高聚物和一种低分子量平光液晶。
• Polymerizable compound and optically anisotropic body
  申请人：DIC Corporation

  公开号：US10723952B2

  公开（公告）日：2020-07-28

  The present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Also provided are a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer. The present invention provides the compound represented by General Formula (I), a composition including the compound, a polymer produced by polymerizing the composition, and an optically anisotropic body including the polymer.

  本发明提供了一种可聚合化合物，该化合物可降低包括该可聚合化合物的可聚合组合物中晶体析出的可能性等，并使该可聚合组合物具有较高的保存稳定性；还提供了一种包括该可聚合化合物的可聚合组合物，该组合物可降低通过聚合该可聚合组合物生产的膜状聚合物中形成不一致性的可能性。本发明还提供了通过聚合该可聚合组合物生产的聚合物和包括该聚合物的光学各向异性体。本发明提供通式（I）代表的化合物、包括该化合物的组合物、通过聚合该组合物生产的聚合物以及包括该聚合物的光学各向异性体。
• Adomeniene, O.; Adomenas, P.; Bernotas, R., Molecular Crystals and Liquid Crystals (1969-1991), 1990, vol. 191, p. 187 - 191
  作者：Adomeniene, O.、Adomenas, P.、Bernotas, R.、Petraitis, J.、Jakubeniene, M.

  DOI：——

  日期：——
• POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY
  申请人：DIC Corporation

  公开号：US20170306233A1

  公开（公告）日：2017-10-26

  The present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Also provided are a polymer-produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer. The present invention provides the compound represented by General Formula (I), a composition including the compound, a polymer produced by polymerizing the composition, and an optically anisotropic body including the polymer.