| 1198798-59-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1198798-59-2
• 化学式: C₃₀H₂₆N₄Ni
• 分子量: 501.253
• InChiKey: CKJZWXJZKJFJRM-WFEKIRLUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Conversion of imine ligands in allyl–nickel(II) complexes

  摘要：

  Interaction of Ni(allyl)(2) and bidentate nitrogen-containing ligands (phenanthroline-1,10; bis(2,6-diisopropylphenyl)diazabutadiene) has been studied. It has been shown that coordination of diimine ligands proceeds with transfer of an allylnickel group to the diimine frame and formation of a covalent Ni-N bond giving rise to imine(amide)Ni(II) complexes. In the case of phenanthroline dearomatization of one heteroaromatic ring takes place. The low-spin imine(amide)allyl complexes(allyl)Ni(C(15)H(15)N(2)) (1) and (allyl)Ni(C(29)H(42)N(2)) (3) have been isolated as crystals and characterized by solution spectroscopy. Combining two molar equivalents of phenanthroline-1,10 with Ni(allyl)(2) results in the transfer of both allyl groups and formation of the high-spin imine(amide)Ni(II) complex Ni(C(15)H(15)N(2))(2) (2). (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.08.010