FeCl2(tris[2-(dimethylphosphino)ethyl]phosphine) | 189447-24-3

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: FeCl2(tris[2-(dimethylphosphino)ethyl]phosphine)
• 英文别名: dichloroiron;tris(2-dimethylphosphanylethyl)phosphane
• CAS: 189447-24-3
• 化学式: C₁₂H₃₀Cl₂FeP₄
• 分子量: 425.018
• InChiKey: NEYNKOPCOLMJFR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  FeCl2(tris[2-(dimethylphosphino)ethyl]phosphine) 以 四氢呋喃 、 甲醇 为溶剂， 生成 FeH(OMe)(tris[2-(dimethylphosphino)ethyl]phosphine)
  参考文献：
  名称：

  Iron Complexes Containing the Tripodal Tetraphosphine Ligand P(CH₂CH₂PMe₂)₃

  摘要：

  The preparation and characterization of iron(II) complexes containing the tripodal tetraphosphine ligand tris[2-(dimethylphosphino)ethyl]phosphine, P(CH2CH2PMe2)(3) (PP3, 1), are reported. The complex FeCl2(PP3) (2) was formed by the reaction of PP3 with anhydrous iron(II) chloride. The complexes FeHCl(PP3) (3) and FeH2(PP3) (4) were formed by the reaction of 2 with Lithium aluminum hydride. Likewise, the complexes FeMeCl(PP3) (5) and FeMe2(PP3) (6) were formed by the reaction of 2 with methyllithium or dimethylmagnesium. Reaction of 2 with CO afforded a mixture of isomeric carbonyl chloride complexes [Fe(CO)Cl(PP3)](+) (7 and 8). Reaction of 2 with PPh3 afforded. [Fe(PPh3)Cl(PP3)](+) (9). The air-sensitive complexes 2-9 were characterized by multinuclear NMR spectroscopy, and 9 was characterized by X-ray crystallography. Crystals of 9 (BPh4 salt), C54H65BClFeP5, M971.09, arts monoclinic, space group P2(1)/c, a = 13.246(3) Angstrom, b = 30.314(2) Angstrom, c = 14.338(2) Angstrom, beta = 100.92(2)degrees, Z = 4; R = 0.058.

  DOI：

  10.1021/ic970030b
• 作为产物：
  描述：

  tris[2-(dimethylphosphino)ethyl]phosphine 、 iron(II) chloride 以 四氢呋喃 为溶剂， 以74%的产率得到FeCl2(tris[2-(dimethylphosphino)ethyl]phosphine)
  参考文献：
  名称：

  Iron Complexes Containing the Tripodal Tetraphosphine Ligand P(CH₂CH₂PMe₂)₃

  摘要：

  The preparation and characterization of iron(II) complexes containing the tripodal tetraphosphine ligand tris[2-(dimethylphosphino)ethyl]phosphine, P(CH2CH2PMe2)(3) (PP3, 1), are reported. The complex FeCl2(PP3) (2) was formed by the reaction of PP3 with anhydrous iron(II) chloride. The complexes FeHCl(PP3) (3) and FeH2(PP3) (4) were formed by the reaction of 2 with Lithium aluminum hydride. Likewise, the complexes FeMeCl(PP3) (5) and FeMe2(PP3) (6) were formed by the reaction of 2 with methyllithium or dimethylmagnesium. Reaction of 2 with CO afforded a mixture of isomeric carbonyl chloride complexes [Fe(CO)Cl(PP3)](+) (7 and 8). Reaction of 2 with PPh3 afforded. [Fe(PPh3)Cl(PP3)](+) (9). The air-sensitive complexes 2-9 were characterized by multinuclear NMR spectroscopy, and 9 was characterized by X-ray crystallography. Crystals of 9 (BPh4 salt), C54H65BClFeP5, M971.09, arts monoclinic, space group P2(1)/c, a = 13.246(3) Angstrom, b = 30.314(2) Angstrom, c = 14.338(2) Angstrom, beta = 100.92(2)degrees, Z = 4; R = 0.058.

  DOI：

  10.1021/ic970030b

文献信息

• Field, Leslie D.; Messerle, Barbara A.; Smernik, Ronald J., Inorganic Chemistry, 1997, vol. 36, # 26, p. 5984 - 5990
  作者：Field, Leslie D.、Messerle, Barbara A.、Smernik, Ronald J.

  DOI：——

  日期：——