| 431073-40-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• CAS: 431073-40-4
• 化学式: C₄₄H₈Cl₈N₁₆NiO₂₄
• 分子量: 1486.95
• InChiKey: BJALRACGMSQWCQ-TUTSKIENSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5,10,15,20-tetra(2,6-dichlorophenyl)porphyrinato nickel(II) 、 硝酸 在 三氟甲磺酸 、 三氟甲磺酸酐 作用下， 以 硝基甲烷 为溶剂， 以36%的产率得到
  参考文献：
  名称：

  One-pot dodecanitration of Zn(II) and Ni(II) meso-tetrakis-(2,6-dichlorophenyl) porphyrin, and extreme redox properties of the obtained complexes

  摘要：

  Introduction of 12 nitro substituents on Zn(II) and Ni(II) [meso-tetra-(2,6-dichlorophenyl)porphyrin = TDCPP] was performed by adapting a recently described method for polynitration of metalloporphyrins, allowing the one-pot synthesis of metallodode-canitroporphyrins from commercially available compounds. The corresponding complexes exhibit the highest reduction potentials ever described for such metalloporphyrins, which are shifted by more than + 1.6 V when compared with those of Zn and Ni(TDCPP The Ni (dodecanitroporphyrin) complex underwent four successive. reversible one-electron reductions between + 470 and 555 mV (vs. SCE). The one-electron reduction product of the Ni dodecanitroporphyrin is stable for hours at room temperature even in aerobic conditions. its visible and EPR spectra indicate a Ni (porphyrin radical anion) structure. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01382-1