1,5-dimethyl-3-trifluoromethylpyrazole-4-carboxylic acid chloride | 1352903-62-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,5-dimethyl-3-trifluoromethylpyrazole-4-carboxylic acid chloride
• 英文别名: 1,5-Dimethyl-3-trifluoromethylpyrazole-4-carbonyl chloride；1,5-dimethyl-3-(trifluoromethyl)pyrazole-4-carbonyl chloride
• CAS: 1352903-62-8
• 化学式: C₇H₆ClF₃N₂O
• 分子量: 226.586
• InChiKey: HCSXBEQRQIGEIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  34.9
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-isobutyl-4-[1-methoxy-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]aniline 、 1,5-dimethyl-3-trifluoromethylpyrazole-4-carboxylic acid chloride 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 N-(3-isobutyl-4-[1-methoxy-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]phenyl)-1,5-dimethyl-3-trifluoromethylpyrazole-4-carboxylic acid amide
  参考文献：
  名称：

  WO2007/20986

  摘要：

  公开号：
• 作为产物：
  描述：

  1,5-dimethyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxylic acid 在 氯化亚砜 作用下， 反应 3.0h， 生成 1,5-dimethyl-3-trifluoromethylpyrazole-4-carboxylic acid chloride
  参考文献：
  名称：

  WO2007/20986

  摘要：

  公开号：

文献信息

• Substituted Pyrazolecarboxylic Acid Anilide Derivative or Salt Thereof, Intermediate Thereof, Agent for Agricultural and Horticultural Use, and Use Thereof
  申请人：Furuya Takashi

  公开号：US20090105325A1

  公开（公告）日：2009-04-23

  The substituted pyrazolecarboxanilide derivatives represented by of the formula (I) wherein R 1 is H, alkyl, alkylcarbonyl, alkenylcarbonyl, cycloalkyl, phenylalkyl, phenylcarbonyl and the like; R 2 is H, halogen, alkyl, CN, OH, alkoxy, phenoxy, phenylthio, phenylsulfonyl and the like; G is alkyl, alkenyl, alkynyl, cycloalkyl, C 3 -C 10 cycloalkenyl and the like; Z is O or S; X is H, halogen, CN, NO 2 , alkyl and the like; Y 1 is H, alkyl, alkenyl, phenyl, alkoxyalkyl and the like; Y 2 is H, halogen, CN, NO 2 , OH, mercapto, amino, carboxyl, C 1 -C 6 alkyl, phenyl, phenoxy, heterocycle and the like, m is 1 or 2; and n is 1-3, and salts thereof exhibit a superior effect as agrohorticultural insecticides or acaricides.

  公式（I）所代表的取代的吡唑羧酰胺衍生物，其中R1为H，烷基，烷基羰基，烯基羰基，环烷基，苯基烷基，苯基羰基等；R2为H，卤素，烷基，CN，OH，烷氧基，苯氧基，苯基硫基，苯基磺酰基等；G为烷基，烯基，炔基，环烷基，C3-C10环烯基等；Z为O或S；X为H，卤素，CN，NO2，烷基等；Y1为H，烷基，烯基，苯基，烷氧基烷基等；Y2为H，卤素，CN， ，OH，巯基，氨基，羧基，C1-C6烷基，苯基，苯氧基，杂环等，m为1或2；n为1-3，以及它们的盐表现出卓越的农业昆虫杀虫剂或杀螨剂的效果。
• Substituted pyrazolecarboxylic acid anilide derivative or salt thereof, intermediate thereof, agent for agricultural and horticultural use, and use thereof
  申请人：Furuya Takashi

  公开号：US08404861B2

  公开（公告）日：2013-03-26

  The substituted pyrazolecarboxanilide derivatives represented by of the formula (I) wherein R1 is H, alkyl, alkylcarbonyl, alkenylcarbonyl, cycloalkyl, phenylalkyl, phenylcarbonyl and the like; R2 is H, halogen, alkyl, CN, OH, alkoxy, phenoxy, phenylthio, phenylsulfonyl and the like; G is alkyl, alkenyl, alkynyl, cycloalkyl, C3-C10 cycloalkenyl and the like; Z is O or S; X is H, halogen, CN, NO2, alkyl and the like; Y1 is H, alkyl, alkenyl, phenyl, alkoxyalkyl and the like; Y2 is H, halogen, CN, NO2, OH, mercapto, amino, carboxyl, C1-C6 alkyl, phenyl, phenoxy, heterocycle and the like, m is 1 or 2; and n is 1-3, and salts thereof exhibit a superior effect as agrohorticultural insecticides or acaricides.

  公式（I）所代表的取代的吡唑羧酰胺衍生物，其中R1为H，烷基，烷基羰基，烯基羰基，环烷基，苯基烷基，苯基羰基等；R2为H，卤素，烷基，CN，OH，烷氧基，苯氧基，苯基硫基，苯基磺酰基等；G为烷基，烯基，炔基，环烷基，C3-C10环烯基等；Z为O或S；X为H，卤素，CN，NO2，烷基等；Y1为H，烷基，烯基，苯基，烷氧基烷基等；Y2为H，卤素，CN， ，OH，巯基，氨基，羧基，C1-C6烷基，苯基，苯氧基，杂环等，m为1或2；n为1-3，及其盐具有卓越的农业园艺杀虫剂或杀螨剂效果。
• SUBSTITUTED PYRAZOLECARBOXYLIC ACID ANILIDE DERIVATIVE OR SALT THEREOF, INTERMEDIATE THEREOF, AGENT FOR AGRICULTURAL AND HORTICULTURAL USE, AND USE THEREOF
  申请人：NIHON NOHYAKU CO., LTD.

  公开号：EP1925613A1

  公开（公告）日：2008-05-28

  The substituted pyrazolecarboxanilide derivatives represented by of the formula (I) wherein R1 is H, alkyl, alkylcarbonyl, alkenylcarbonyl, cycloalkyl, phenylalkyl, phenylcarbonyl and the like; R2 is H, halogen, alkyl, CN, OH, alkoxy, phenoxy, phenylthio, phenylsulfonyl and the like; G is alkyl, alkenyl, alkynyl, cycloalkyl, C3-C10 cycloalkenyl and the like; Z is O or S; X is H, halogen, CN, NO2, alkyl and the like; Y1 is H, alkyl, alkenyl, phenyl, alkoxyalkyl and the like; Y2 is H, halogen, CN, NO2, OH, mercapto, amino, carboxyl, C1-C6 alkyl, phenyl, phenoxy, heterocycle and the like, m is 1 or 2; and n is 1-3, and salts thereof exhibit a superior effect as agrohorticultural insecticides or acaricides.

  式 (I) 所代表的取代的吡唑甲酰苯胺衍生物 其中 R1 是 H、烷基、烷基羰基、烯基羰基、环烷基、苯基烷基、苯基羰基等；R2 是 H、卤素、烷基、CN、OH、烷氧基、苯氧基、苯硫基、苯磺酰基等；G 是烷基、烯基、炔基、环烷基、C3-C10 环烯基等；Z 是 O 或 S；X 是 H、卤素、CN、NO2、烷基等；Y1 是 H、烷基、烯基、苯基、烷氧基烷基等；Y2 是 H、卤素、CN、 、OH、巯基、氨基、羧基、C1-C6 烷基、苯基、苯氧基、杂环等，m 是 1 或 2；n 是 1-3，其盐类作为农业园艺杀虫剂或杀螨剂具有优异的效果。
• US8404861B2
  申请人：——

  公开号：US8404861B2

  公开（公告）日：2013-03-26