(11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione)bis(2-phenylpyridine)iridium(III) | 1123496-31-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione)bis(2-phenylpyridine)iridium(III)
• CAS: 1123496-31-0
• 化学式: C₄₅H₄₉Br₂IrN₂O₄
• 分子量: 1033.92
• InChiKey: KYINTDVEAFEEQY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [iridium(III)(μ-chloro)(2-phenylpyridine)2]2 、 11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione 在 Et₃N 、 AgCF₃COO 作用下， 以 丙酮 为溶剂， 以48%的产率得到(11-(2,5-dibromo-4-hexyloxy-phenoxy)-undecane-2,4-dione)bis(2-phenylpyridine)iridium(III)
  参考文献：
  名称：

  Towards a phosphorescent cyclometalated iridium complex containing a modified polymerizable acetylacetonato ligand

  摘要：

  A convenient synthesis of the complex [Ir(ppy)(2)(phC6-acac)] (1, ppy = 2-phenylpyridyl, phC6-acac = 11-(2,5-dibromo-4-hexyloxyphenoxy)-undecane-2,4-dione) from [{Ir(mu-Cl)(ppy)(2)}(2)], phC6-acacH and silver trifluoroacetate as the halide abstractor in refluxing acetone is described. The crystal and molecular structure of I was determined by X-ray crystallography. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.10.029