bis(1,10-phenanthroline) copper(I) perchlorate | 23624-03-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: bis(1,10-phenanthroline) copper(I) perchlorate
• 英文别名: [Cu(1,10-phenanthroline)2](perchlorate)；{Cu(phen)2}ClO4；Bis(1,10-phenanthroline)copper(i) perchlorate；copper(1+);1,10-phenanthroline;perchlorate
• CAS: 23624-03-5
• 化学式: C₂₄H₁₆CuN₄*ClO₄
• 分子量: 523.414
• InChiKey: SHLNXUHDRSLKQW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.81
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  126
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  {(1,10-phenantholine)salicylaldehydato copper(II)}2 {perchlorate}2 以 甲醇 为溶剂， 生成 bis(1,10-phenanthroline) copper(I) perchlorate
  参考文献：
  名称：

  Garland, M. T.; Grandjean, D.; Spodine, E., Acta Crystallographica, Section C: Crystal Structure Communications, 1987, vol. 43, p. 1910 - 1912

  摘要：

  DOI：

文献信息

• Influence of the counterion on the geometry of Cu(I) and Cu(II) complexes with 1,10-phenanthroline
  作者：Alessandra Crispini、Carmen Cretu、Diana Aparaschivei、Adelina A. Andelescu、Viorel Sasca、Valentin Badea、Iolinda Aiello、Elisabeta I. Szerb、Otilia Costisor

  DOI：10.1016/j.ica.2017.05.064

  日期：2018.1

  respectively. The firstly isolated Cu(I) complexes were characterized by IR, 1H NMR and UV-Vis spectroscopies, their proposed structures being confirmed by elemental analysis, atomic absorption spectroscopy (AAS) and thermogravimetric analysis (TGA). The molecular structure of Cu(II) complexes was determined by single crystal X-ray diffraction analysis. While for Cu(I) complexes, the coordinating nature

  摘要研究了抗衡离子对Cu（I）和Cu（II）未取代的phen基（phen = 1,10-菲咯啉）配合物的几何构型的影响。所使用的合成策略提供了具有通式[（phen）2Cu] + Y-（Y- = ClO4-，I-，SCN-和BF4-）的四配位Cu（I）和五配位Cu（II）的合成。和[（phen）2CuX] + Y-（X = Cl-，I-，NCS-和Y- = -，I-，SCN-和 -）。首次分离的Cu（I）配合物通过IR，1H NMR和UV-Vis光谱学进行表征，其提议的结构已通过元素分析，原子吸收光谱法（AAS）和热重分析（TGA）得以确认。通过单晶X射线衍射分析确定了Cu（II）配合物的分子结构。对于Cu（I）络合物，
• Gill, Dip Singh; Pathania, Vivek; Vermani, Bal Krishan, Zeitschrift fur Physikalische Chemie, 2003, vol. 217, # 6, p. 739 - 749
  作者：Gill, Dip Singh、Pathania, Vivek、Vermani, Bal Krishan、Sharma, Raj Pal

  DOI：——

  日期：——
• Assignment of the charge-transfer excited states of bis(N-heterocyclic) complexes of copper(I)
  作者：W. L. Parker、G. A. Crosby

  DOI：10.1021/j100352a012

  日期：1989.7
• Synthesis and characterization of derivatives of copper(I) with N- and S-donor ligands
  作者：Claudio Pettinari、Riccardo Pettinari、Maura Pellei、Giancarlo Gioia Lobbia

  DOI：10.1016/s0277-5387(99)00089-3

  日期：1999.5

  New copper(I) complexes of the type [(PBz(3))L3Cu]X, (PBz(3))L2CuX, [(PBz(3))(2)L2Cu]X, [(PBz(3))(3)LCu]X (L=monodentate N-donor imidazole- or pyrazole-type ligand, Bz=benzyl, X=NO3 or ClO4), (PBz(3))(y)(N-N)(x)CuNO3 (N-N=bis(pyrazol-1-yl)methane, x=y=1; N-N=bis(1,2,4-triazol-1-yl)methane, x=y=2), (PPh3)L-2'CuX, (PPh3)(2)L'CuX, [(PPh3)L-3'Cu]X and (PPh3)L'CuX, (L'=monodentate S-donor 1-methyl-imidazoline-2(3H)-thione or imidazoline-2(1,3H)-thione) were obtained from the reaction of (PR3)(n)CuX with the appropriate N- or S-donor ligand. Reaction between [(PPh3)(n)Cu(L)(m)]X with PBz(3) often resulted in the formation of new [(PBz(3))(z)Lm-1Cu]X (z=n or n+1) complexes upon displacement of one molecule of L and two or three molecules of PPh3, whereas reaction of [(N-N)(2)Cu]ClO4 with PBz(3) and 1,10-phenanthroline (Phen) yielded [(PBz(3))(2)CuClO4] and [(Phen)(2)Cu]ClO4, respectively, upon displacement of both molecules of bidentate chelating ligands. No reaction occurred between (PPh3)L-2'CuX, (PPh3)(2)L'CuX or [(PPh3)L-3'Cu]X and PBz(3). All the derivatives obtained were characterized by IR spectroscopy, H-1 NMR, and conductance studies, and in some cases also by molecular weight measurements. (C) 1999 Elsevier Science Ltd. All rights reserved.