(+/-)-(E)-4-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-buten-2-one | 170710-62-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (+/-)-(E)-4-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-buten-2-one
• 英文别名: (E)-4-(6-ethyl-2,6-dimethylcyclohexen-1-yl)but-3-en-2-one
• CAS: 170710-62-0
• 化学式: C₁₄H₂₂O
• 分子量: 206.328
• InChiKey: GBQRBJSOVCABNI-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  甲氧羰基亚甲基三苯基正膦 、 (+/-)-(E)-4-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-buten-2-one 反应 2.0h， 生成 (+/-)-(2Z,4E)-methyl 5-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-methyl-2,4-pentadienoate 、 (+/-)-(2E,4E)-methyl 5-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-methyl-2,4-pentadienoate
  参考文献：
  名称：

  Nakano, Sei-ichi; Todoroki, Yasushi; Hirai, Nobuhiro, Bioscience, Biotechnology and Biochemistry, 1995, vol. 59, # 9, p. 1699 - 1706

  摘要：

  DOI：
• 作为产物：
  描述：

  (+/-)-4-(6'-ethyl-1'-hydroxy-2',6'-dimethylcyclohexyl)-but-3-yn-2-ol 在 manganese(IV) oxide 、 红铝 、 三氯氧磷 作用下， 以 四氢呋喃 、 吡啶 、 二氯甲烷 、 甲苯 为溶剂， 反应 25.5h， 生成 (+/-)-(E)-4-(6'-ethyl-2',6'-dimethyl-1'-cyclohexene-1'-yl)-3-buten-2-one
  参考文献：
  名称：

  Nakano, Sei-ichi; Todoroki, Yasushi; Hirai, Nobuhiro, Bioscience, Biotechnology and Biochemistry, 1995, vol. 59, # 9, p. 1699 - 1706

  摘要：

  DOI：

文献信息

• CURABLE COMPOSITION, CURED SUBSTANCE, OPTICAL MEMBER, AND LENS
  申请人：FUJIFILM Corporation

  公开号：US20220315686A1

  公开（公告）日：2022-10-06

  Provided is a curable composition containing a polymerizable compound represented by General Formula (A), an acylphosphine oxide photopolymerization initiator, and an amine compound. Ar L-Sp-Pol) n Genera Formula (A) Ar represents an n-valent group containing a nitrogen-containing fused aromatic ring satisfying all items (i) to (iii), as a partial structure. (i) The nitrogen-containing fused aromatic ring has a fused ring structure in which two or more 6-membered rings are fused. (ii) The nitrogen-containing fused aromatic ring has at least one nitrogen atom as a ring-constituting atom. (iii) All ring-constituting atoms have p-orbitals, and all the p-orbitals contribute to aromaticity. L and Sp each independently represent a single bond or a divalent linking group, Pol represents a hydrogen atom or a polymerizable group, and n represents 1 or 2. The polymerizable compound represented by General Formula (A) contains at least one polymerizable group.