(1,1'-(1,4-butanediyl)bis(imidazole))(oxalato)manganese(II) | 1092535-41-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (1,1'-(1,4-butanediyl)bis(imidazole))(oxalato)manganese(II)
• CAS: 1092535-41-5
• 化学式: C₂O₄*C₁₀H₁₄N₄*Mn
• 分子量: 333.206
• InChiKey: RPUMTXKIPOQVOH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.96
• 重原子数：
  21.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  115.9
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  manganese(II)carbonate 、 双咪唑丁烷 、 oxalic acid dihydrate 以 乙醇 、 水 为溶剂， 以69%的产率得到(1,1'-(1,4-butanediyl)bis(imidazole))(oxalato)manganese(II)
  参考文献：
  名称：

  Syntheses and characterizations of nine coordination polymers of transition metals with carboxylate anions and bis(imidazole) ligands

  摘要：

  Nine new compounds, namely [CuL1(biim-6)] center dot H2O (1), [ZnL1(biim-6)] center dot H2O (2), [MnL1(biim-6)] center dot H2O (3), [MnL1(biim-4)] (4), [CO2(L2)(2)(biim-5)(3) center dot 6H(2)O] center dot 8H(2)O (5), [ZnL3(biim-6)] (6), [ZnL3(biim-5)] (7), [CdL3(biim-5) center dot 1.5H(2)O] center dot 0.5H(2)O (8) and [CdL4(biim-6) center dot 2H(2)O] (9) [where L1 = oxalate anion, L2 = fumarate anion, L3 = phthalate anion, L4 = p-phthalate anion, biim-4 = 1,1'-(1,4-butanediyl)bis(imidazole), biim-5 = 1,1'-(1,5-pentanedidyl)bis(imidazole) and biim-6 = 1,1'-(1,6-hexanedidyl)bis(imidazole)I were successfully synthesized. Compounds 1-3 are isostructural, and display 2D polymeric structures. Compound 4 shows a threefold interpenetrating diamondoid framework. In compound 5, the anions act as counterions, and the metal cations are bridged by bis(imidazole) ligands to form I D polymeric chains. Compounds 6-9 show 2D polymeric structures. The magnetic properties for 1, 3 and 4 and luminescent properties for 2 and 6-9 are discussed. Thermogravimetric analyses (TGA) for these compounds are also discussed. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.07.026