tetraethylene glycol monododecyl ether sodium salt | 138714-62-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tetraethylene glycol monododecyl ether sodium salt
• CAS: 138714-62-2
• 化学式: C₂₀H₄₁O₅*Na
• 分子量: 384.532
• InChiKey: MXTALHPJCDHZQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.34
• 重原子数：
  26.0
• 可旋转键数：
  22.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  59.98
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  tetraethylene glycol monododecyl ether sodium salt 、 碘甲烷 以 四氢呋喃 为溶剂， 以95%的产率得到tetraethylene glycol methyl dodecyl ether
  参考文献：
  名称：

  Catalytic activity of cyclophosphazenic polypodands in phase-transfer reactions. Comparison with open-chain analogues.

  摘要：

  The catalytic activity of cyclophosphazenic polypodans 1a-c was evaluated in typical reactions performed under solid-liquid (SL) and liquid-liquid (LL) phase-transfer catalysis (PTC) conditions. Such activity is largely determined by the complexation extent of 1a-c, which is, in turn, related to the number of binding sites of the ligand (1a < 1b less-than-or-equal-to 1c) and to the nature of the inorganic salt M+Y- (Na+ > K+ >> Rb+ and SCN- approximately I- > Br-). Also the presence of water was found to play an important role. Comparison with open-chain analogues PEG 2 and TRIDENT 3 showed that polypodands 1a-c, due to their excellent stability, simplicity of preparation and high complexing ability, can be considered promising phase transfer catalysts, especially under SL-PTC conditions.

  DOI：

  10.1016/s0040-4020(01)89750-7