[Co(OAc)(15,15-difluoro-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione(-2H))]*H2O | 1356598-36-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Co(OAc)(15,15-difluoro-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione(-2H))]*H2O
• 英文别名: [Co(OAc)(F2dione)]*H2O
• CAS: 1356598-36-1
• 化学式: C₁₃H₂₂CoF₂N₅O₄*H₂O
• 分子量: 427.354
• InChiKey: VEGGRJGKZUPCDA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  15,15-difluoro-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione 、 cobalt(III) acetylacetonate 、 水 以 乙腈 为溶剂， 以27%的产率得到[Co(OAc)(15,15-difluoro-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione(-2H))]*H2O
  参考文献：
  名称：

  Nickel and cobalt complexes of 15,15-disubstituted 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione ligands

  摘要：

  The synthesis of the novel Co(III)(15,15-difluoro-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione) acetate complex from different cobalt sources is described. Furthermore, the corresponding nickel complex and its new analog with the 15-fluoro-15-methyl-1,4,7,10,13-pentaazacyclohexadecane-14,16-dione ligand were studied in great detail including cyclic voltammetry and single crystal analyses of a total of 6 complexes. The results for the nickel compounds showed that depending upon ligand substitution and solvent, an N3 or, after a double deprotonation, an N5 coordination mode could be observed and characterized in the solid state and in solution. Moreover, cyclic voltammetric analyses were performed revealing that the Ni(II/III) oxidation potentials are becoming more positive with the increasing number of fluorine atoms. This effect is due to the electron withdrawing property of fluorine that is reducing the electron richness of the metal ion. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.004