3,6-diiodo-9-(4-methoxyphenyl)-9H-carbazole | 878675-11-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-diiodo-9-(4-methoxyphenyl)-9H-carbazole
• 英文别名: 3,6-Diiodo-9-(4-methoxyphenyl)carbazole
• CAS: 878675-11-7
• 化学式: C₁₉H₁₃I₂NO
• 分子量: 525.127
• InChiKey: AUHVZHQPPDBEGE-UHFFFAOYSA-N

物化性质

• 熔点：
  186.0-188.0 °C(Solv: tetrahydrofuran (109-99-9))
• 沸点：
  567.4±50.0 °C(Predicted)
• 密度：
  1.90±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  14.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,6-diiodo-9-(4-methoxyphenyl)-9H-carbazole 在 potassium phosphate 、 copper(l) iodide 、 trans-1,2-Diaminocyclohexane 、 三溴化硼 作用下， 以 1,4-二氧六环 为溶剂， 反应 26.25h， 生成 4-(3,6-di(9H-carbazol-9-yl)-9H-carbazol-9-yl)phenol
  参考文献：
  名称：

  Dendron engineering in self-host blue iridium dendrimers towards low-voltage-driving and power-efficient nondoped electrophosphorescent devices

  摘要：

  通过提高树枝状化合物的 HOMO 能级，有利于有效注入空穴并促进激子的形成，实现了低电压驱动和高能效的非掺杂电磷光器件。

  DOI：

  10.1039/c6cc08722a
• 作为产物：
  描述：

  咔唑 在 potassium iodate 、 potassium phosphate 、 copper(l) iodide 、 溶剂黄146 、 potassium iodide 、 trans-1,2-cyclohexanediamine 作用下， 以 1,4-二氧六环 为溶剂， 反应 32.0h， 生成 3,6-diiodo-9-(4-methoxyphenyl)-9H-carbazole
  参考文献：
  名称：

  高效无掺杂溶液处理的磷光OLED的铱铱树枝状大分子中电荷平衡的单分子调节。

  摘要：

  通过将p型树状体，n型树状体和蓝色发光Ir核整合到一个树状平台中，已证明了电荷平衡的单个分子调节。和....相比...

  DOI：

  10.1039/c6cc05165k

文献信息

• N-phenyl triscarbazole
  申请人：Solvay SA

  公开号：EP2433928A1

  公开（公告）日：2012-03-28

  The present invention relates to a novel triscarbazole compound having substituent on N-phenyl, which can be represented by Formula (I). wherein R1 is selected from the group consisting of halogen or alkyl or alkoxy group having 1 to 20 carbon atoms wherein one or more hydrogen atom may be replaced by halogen; RA, RB, Rc, RD and RE are any of substituents; and i, j, k, l and m are same or different at each occurrence and represent an integer from 0 to 4. By introduction of the substituent on N-phenyl, the device efficiency, stability and lifetime can be increased while maintaining the solubility. These compounds can be used in various organic devices such as organic light emitting diodes, photovoltaic cells or organic semiconductor devices.

  本发明涉及一种在N-苯基上具有取代基的新型三咔唑化合物，其可以用式（I）表示。其中R1选自卤素、烷基或含有1至20个碳原子的烷氧基团，其中一个或多个氢原子可被卤素取代；RA、RB、Rc、RD和RE是任意的取代基；i、j、k、l和m在每次出现时相同或不同，并表示从0到4的整数。通过在N-苯基上引入取代基，可以提高器件的效率、稳定性和寿命，同时保持溶解性。这些化合物可用于各种有机器件，如有机发光二极管、光伏电池或有机半导体器件。
• [EN] N-PHENYL TRISCARBAZOLE<br/>[FR] N-PHÉNYL TRISCARBAZOLE
  申请人：SOLVAY

  公开号：WO2012025510A1

  公开（公告）日：2012-03-01

  The present invention relates to a novel triscarbazole compound having substituent on N-phenyl, which can be represented by Formula (I). wherein R1 is selected from the group consisting of hydrogen, halogen or alkyl or alkoxy group having 1 to 20 carbon atoms wherein at least one hydrogen atom is optionally replaced by halogen; RA, RB, RC, RD and RE are any of substituents other than hydrogen wherein at least two of R1 and RA may further form a fused ring; and i, j, k, l and m are same or different at each occurrence and represent an integer from 0 to 4, with the proviso that when R1 is hydrogen, i is not 0. By introduction of the substituent on N-phenyl, the device efficiency, stability and lifetime can be increased while maintaining the solubility. These compounds can be used in various organic devices such as organic light emitting diodes, photovoltaic cells or organic semiconductor devices.

  本发明涉及一种具有N-苯基上取代基的新型三咔唑化合物，可以用化学式（I）表示。其中R1选自氢、卤素或具有1至20个碳原子的烷基或烷氧基组成的基团，其中至少有一个氢原子可以被卤素取代；RA、RB、RC、RD和RE是除氢之外的任何取代基，其中至少有两个R1和RA可以进一步形成融合环；i、j、k、l和m在每次出现时相同或不同，并表示0至4的整数，但当R1为氢时，i不为0。通过在N-苯基上引入取代基，可以增加器件的效率、稳定性和寿命，同时保持溶解性。这些化合物可用于各种有机器件，如有机发光二极管、光伏电池或有机半导体器件。
• [EN] HOST MATERIAL FOR LIGHT-EMITTING DIODES<br/>[FR] MATIÈRE HÔTE POUR DIODES ÉLECTROLUMINESCENTES
  申请人：SOLVAY

  公开号：WO2010043693A1

  公开（公告）日：2010-04-22

  The present invention relates to a host material comprising a compound having two carbazole moieties which is suitable for blue-emitting OLEDs. Surprisingly, it has been found that when appropriate substituents are present in the carbazole structure, the solubility of the compounds can be improved without any adverse effect on the OLED performance. The present invention further relates to the use of the host materials and to an organic light emitting device comprising the host material.

  本发明涉及一种包含具有两个咔唑基团的化合物的主体材料，适用于发出蓝光的OLED。令人惊讶的是，发现当适当的取代基存在于咔唑结构中时，化合物的溶解性可以得到改善，而不会对OLED性能产生不良影响。本发明还涉及主体材料的使用以及包含主体材料的有机发光器件。
• Aromatic heterocyclic-based charge transport materials having two amino groups
  申请人：Matoliukstyte Ausra

  公开号：US20060051690A1

  公开（公告）日：2006-03-09

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic heterocyclic group; X is a bond or a linking group; E comprises a reactive ring group or a reactive functional group; and R 1 , R 2 , R 3 , and R 4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and bridged charge transport materials derived form the charge transport material above are also described.

  改进的有机光受体包括一个电导基底和一个位于电导基底上的光电传导元件，光电传导元件包括：(a) 具有以下结构的电荷传输材料，其中Y包括芳香杂环基团；X是一个键或一个连接基团；E包括一个反应性环基团或一个反应性官能基团；以及R1、R2、R3和R4，每个独立地包括H、烷基基团、酰基、醚基、烯基基团、炔基基团、杂环基团、芳香基团或环基的一部分；以及(b) 一个电荷生成化合物。还描述了相应的静电复印设备、静电复印成像方法和由上述电荷传输材料衍生的桥接电荷传输材料。
• Host material for light-emitting diodes
  申请人：Martin Roland

  公开号：US20110198579A1

  公开（公告）日：2011-08-18

  The present invention relates to a host material comprising a compound having two carbazole moieties which is suitable for blue-emitting OLEDs. Surprisingly, it has been found that when appropriate substituents are present in the carbazole structure, the solubility of the compounds can be improved without any adverse effect on the OLED performance. The present invention further relates to the use of the host materials and to an organic light emitting device comprising the host material.

  本发明涉及一种主体材料，包括一种具有两个咔唑基团的化合物，适用于蓝色发光的OLED。令人惊讶的是，发现当咔唑结构中存在适当的取代基时，化合物的溶解性能可以得到改善，而不会对OLED性能产生任何不良影响。本发明还涉及主体材料的使用以及包括主体材料的有机发光装置。