3,6-bis(5-methoxyindol-1-yl)-9-(4-methoxyphenyl)carbazole | 1472023-76-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-bis(5-methoxyindol-1-yl)-9-(4-methoxyphenyl)carbazole
• 英文别名: 3,6-Bis(5-methoxyindol-1-yl)-9-(4-methoxyphenyl)carbazole
• CAS: 1472023-76-9
• 化学式: C₃₇H₂₉N₃O₃
• 分子量: 563.656
• InChiKey: KSHKLLDAYBORLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  43
• 可旋转键数：
  6
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  9-(4-甲氧基苯基)咔唑 在 potassium iodate 、 18-冠醚-6 、 铜 、 potassium carbonate 、 potassium iodide 作用下， 以 邻二氯苯 为溶剂， 生成 3,6-bis(5-methoxyindol-1-yl)-9-(4-methoxyphenyl)carbazole
  参考文献：
  名称：

  3,6-Bis(indol-1-yl)-9-phenylcarbazoles as electroactive materials for electrophosphorescent diodes

  摘要：

  Four derivatives of 3,6-bis(indol-1-yl)-9-phenylcarbazole were synthesized by Ullmann-type coupling including those having methoxy groups at the different positions. Thermal, optical and photophysical properties of the synthesized materials were studied. All the synthesized 3,6-bis(indol-1-yl)-9-phenylcarbazoles are capable of glass formation with the glass transition temperatures ranging from 77 to 95 degrees C. They exhibit high thermal stability with the 5% weight loss temperatures ranging from 393 to 459 degrees C. Photoluminescence spectra of the dilute solutions of 3,6-bis(indol-1-yl)-9-phenylcarbazoles are characterized by two well-resolved vibrational peaks at ca. 390 nm and 405 nm. The solid films of the materials also exhibit well-resolved vibrational peaks, however the wavelengths of the maxima are red-shifted by ca. 10 nm. 3,6-Bis(indol-1-yl)-9-phenylcarbazoles were tested in the single-layer organic light emitting diodes as active materials and in phosphorescent light emitting diodes as host materials of emitting layers in combination with Ir(Fppy)(3) as a guest phosphor. Blue single-layer electroluminescent and electrophosphorescent devices with current efficiencies of 3.7-4.1 cd/A and 10.8-12.6 cd/A respectively were fabricated. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.07.020

文献信息

• 3,6-Bis(indol-1-yl)-9-phenylcarbazoles as electroactive materials for electrophosphorescent diodes
  作者：J. Keruckas、J.V. Grazulevicius、D. Volyniuk、V. Cherpak、P. Stakhira

  DOI：10.1016/j.dyepig.2013.07.020

  日期：2014.1

  Four derivatives of 3,6-bis(indol-1-yl)-9-phenylcarbazole were synthesized by Ullmann-type coupling including those having methoxy groups at the different positions. Thermal, optical and photophysical properties of the synthesized materials were studied. All the synthesized 3,6-bis(indol-1-yl)-9-phenylcarbazoles are capable of glass formation with the glass transition temperatures ranging from 77 to 95 degrees C. They exhibit high thermal stability with the 5% weight loss temperatures ranging from 393 to 459 degrees C. Photoluminescence spectra of the dilute solutions of 3,6-bis(indol-1-yl)-9-phenylcarbazoles are characterized by two well-resolved vibrational peaks at ca. 390 nm and 405 nm. The solid films of the materials also exhibit well-resolved vibrational peaks, however the wavelengths of the maxima are red-shifted by ca. 10 nm. 3,6-Bis(indol-1-yl)-9-phenylcarbazoles were tested in the single-layer organic light emitting diodes as active materials and in phosphorescent light emitting diodes as host materials of emitting layers in combination with Ir(Fppy)(3) as a guest phosphor. Blue single-layer electroluminescent and electrophosphorescent devices with current efficiencies of 3.7-4.1 cd/A and 10.8-12.6 cd/A respectively were fabricated. (C) 2013 Elsevier Ltd. All rights reserved.