[(salhexPh₂)Cu] | 1415221-39-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(salhexPh₂)Cu]
• CAS: 1415221-39-4
• 化学式: C₃₂H₂₈CuN₂O₂
• 分子量: 536.133
• InChiKey: OBCZYODZVFVGMU-KECHZXEWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (1R,2R)-N,N′-bis(3-phenylsalicylidene)-1,2-cyclohexanediamine 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 反应 16.0h， 以76%的产率得到[(salhexPh₂)Cu]
  参考文献：
  名称：

  Redox chemistry of copper complexes with various salen type ligands

  摘要：

  The two essential redox processes in Cu(II) salen (and salan) complexes Cu(II)/Cu(I) and [PhO](center dot)/[PhO[-]] were studied by electrochemical and spectroelectrochemical (UV-Vis-absorption or EPR) techniques on a series of complexes in which the salen (salan) type ligands bear various substituents R = H, F, Ph, tBu or CH3 on the linker C- or N-atoms or on the phenol core. The substitution pattern can be related to the stability of the phenoxy radicals. The geometry of the complexes (especially around the Cu atom) could be established by XRD for the new complex [(Me(2)salhexF(4))Cu] {H-2(Me(2)salhexF(4)) = (1R,2R)-N,N'-bis(2-hydroxy-3,5-di-fluoro-acetophenonylidene)-cyclohexane-1,2-diamine} in the solid and for all other derivatives by EPR in fluid solution. Also, the application of the complexes in oxidation catalysis was tested using the oxidation of benzyl alcohol. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.08.016