[Pb(μ-8-Quin)I]₂ | 1431622-00-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Pb(μ-8-Quin)I]₂
• 英文别名: [Pb(μ-8-(8-hydroxyquinoline-H))I]₂；lead(2+);quinolin-8-olate;diiodide
• CAS: 1431622-00-2
• 化学式: C₁₈H₁₂I₂N₂O₂Pb₂
• 分子量: 956.514
• InChiKey: RJJSUCZIBPTNDB-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -4.14
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [Pb(μ-8-Quin)I]₂ 以 neat (no solvent, solid phase) 为溶剂， 生成 lead(II) oxide
  参考文献：
  名称：

  Fabrication of an organic light-emitting diode (OLED) from a two-dimensional lead(II) coordination polymer

  摘要：

  A new two-dimensional lead(II) coordination polymer, {[Pb((mu-Q)I](2)}(n), was prepared by reacting lead(II) iodide with 8-hydroxyquinoline (HQ) in a fast and facile process. The complex was fully characterized based on its H-1 NMR, IR and UV spectra, single crystal X-ray diffraction analysis and elemental analysis. The crystal structure showed that the compound is a two-dimensional coordination polymer consisting of dimeric units with a building block of [Pb-2(mu-Q)(2)I-2]. The lead atoms are four-coordinated, and the HQ ligand acted as a bidentate chelate, along with a bridging phenoxy oxygen and iodine atoms. Application of the prepared complex in the fabrication of OLEDs in two different concentrations has been demonstrated. The current-voltage (I-V) characteristics and the photoluminescence (PL) and electroluminescence (EL) properties of the complex have been investigated. The EL of the compound has exhibited a green emission at 555 and 532 nm for ratios of, 100:20 and 100:35 (PVK/[Pb((mu-Q)I](2)), respectively. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.01.009
• 作为产物：
  描述：

  8-羟基喹啉 、 lead(II) iodide 以 甲醇 为溶剂， 反应 336.0h， 以80%的产率得到[Pb(μ-8-Quin)I]₂
  参考文献：
  名称：

  Fabrication of an organic light-emitting diode (OLED) from a two-dimensional lead(II) coordination polymer

  摘要：

  A new two-dimensional lead(II) coordination polymer, {[Pb((mu-Q)I](2)}(n), was prepared by reacting lead(II) iodide with 8-hydroxyquinoline (HQ) in a fast and facile process. The complex was fully characterized based on its H-1 NMR, IR and UV spectra, single crystal X-ray diffraction analysis and elemental analysis. The crystal structure showed that the compound is a two-dimensional coordination polymer consisting of dimeric units with a building block of [Pb-2(mu-Q)(2)I-2]. The lead atoms are four-coordinated, and the HQ ligand acted as a bidentate chelate, along with a bridging phenoxy oxygen and iodine atoms. Application of the prepared complex in the fabrication of OLEDs in two different concentrations has been demonstrated. The current-voltage (I-V) characteristics and the photoluminescence (PL) and electroluminescence (EL) properties of the complex have been investigated. The EL of the compound has exhibited a green emission at 555 and 532 nm for ratios of, 100:20 and 100:35 (PVK/[Pb((mu-Q)I](2)), respectively. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.01.009