Pd(8-quinolinolate)2 | 35820-08-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Pd(8-quinolinolate)2
• 英文别名: bis (8-oxyquinoline) palladium (II)；Bis(8-oxyquinoline) palladium (II)；palladium(2+);quinolin-8-olate
• CAS: 35820-08-7
• 化学式: C₁₈H₁₂N₂O₂Pd
• 分子量: 394.725
• InChiKey: LQWYGAYGGJZQAX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.61
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Pd(8-quinolinolate)2 以 乙腈 为溶剂， 生成 quinolin-8-ol; palladium(II)-salt
  参考文献：
  名称：

  Thin-film conducting polymers based on Ni(II), Pd(II), and Pt(II) complexes with 8-quinolinol

  摘要：

  New thin polymeric films were prepared electrochemically on the basis of Ni(II), Pd(II), and Pt(II) complexes with 8-quinolinol, and conditions of synthesis were optimized. Basic characteristics of the films such as the thickness, charge transfer rate in the polymeric matrix, and photovoltaic effect were determined.

  DOI：

  10.1134/s1070427207080332
• 作为产物：
  描述：

  8-羟基喹啉 、 tetramminepalladium(II) chloride 以 乙醇 、 水 为溶剂， 生成 Pd(8-quinolinolate)2
  参考文献：
  名称：

  Bargellini; Bellucci, Gazzetta Chimica Italiana, 1923, vol. 53, p. 609

  摘要：

  DOI：

文献信息

• Supramolecular Chemistry:  Molecular Recognition and Self-Assembly Using Rigid Spacer-Chelators Bearing Cofacial Terpyridyl Palladium(II) Complexes Separated by 7 Å
  作者：Roger D. Sommer、Arnold L. Rheingold、Andrew J. Goshe、B. Bosnich

  DOI：10.1021/ja004279v

  日期：2001.5.1

  These palladium complexes readily form large molecular rectangles with a linear linker such as 4,4'-dipyridyl. The dichlorodipalladium complex of the partially reduced spacer-chelator is capable of incarcerating planar aromatic and coordination compounds as guests. A crystal structure showing the incorporation of 9-methylanthracene has been determined. A 9-methylanthracene lies completely within the approximately

  已经制备了带有两个对称结合的三联吡啶螯合剂的部分和完全芳族分子间隔基。构建这些间隔螯合剂以将两个三联吡啶配体及其与方形平面金属的配合物共面处理，两种金属之间的间距约为 7 。制备并表征了这些间隔-螯合剂的二钯 (II) 配合物。这些钯配合物很容易形成带有线性接头（例如 4,4'-二吡啶基）的大分子矩形。部分还原的间隔-螯合剂的二氯二钯络合物能够将平面芳香族和配位化合物作为客体嵌入。已确定显示掺入 9-甲基蒽的晶体结构。9-甲基蒽完全位于由两个共面布置的氯-钯-三联吡啶单元形成的裂缝提供的大约7A空间内。晶体结构显示了第二个 9-甲基蒽和相邻受体之间的额外 pi 堆积相互作用。
• Umapathy, P.; Chandrasekhar, S.; Ghuge, K. D., Journal of the Indian Chemical Society, 1981, vol. 58, p. 220 - 224
  作者：Umapathy, P.、Chandrasekhar, S.、Ghuge, K. D.

  DOI：——

  日期：——
• Macrocyclic Aromatic Ether-Imide-Sulfones:  Versatile Supramolecular Receptors with Extreme Thermochemical and Oxidative Stability
  作者：Howard M. Colquhoun、David J. Williams、Zhixue Zhu

  DOI：10.1021/ja027851m

  日期：2002.11.1

  Macrocyclic receptors having extreme thermo-oxidative stability, and which bind a wide range of electron-donor substrates via pi-stacking donor-acceptor interactions, are accessible by cycloimidization of an amine-functionalized aryl ether-sulfone with pyromellitic dianhydride or 1,4,5,8-naphthalenetetracarboxylic dianhydride. The potential of these receptors in supramolecular chemistry is illustrated, for example, by the spontaneous self-assembly and crystallization of a five-component [3]pseudorotaxane from a solution of its constituents.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pd: MVol.2, 123, page 403 - 405
  作者：

  DOI：——

  日期：——
• Homogeneous and heterogeneous dehydrogenation reactions of cyclooctane with palladium(II) complexes as catalysts
  作者：Sandra Taubmann、Helmut G. Alt

  DOI：10.1016/j.molcata.2008.04.011

  日期：2008.6

  A series of new palladium(II) complexes with heteroatomic chelating ligands (carboxylates and alcoholates) was synthesized. The catalytic activities of the palladium complexes were successfully tested for catalytic CH-activation reactions of cyclooctane. They gave TONs of 2.6-26.5 (300 degrees C, 16 h) in homogeneous solution and 4.6-21.4 (400 degrees C, 5 h) in heterogeneous reactions. (C) 2008 Elsevier B.V. All rights reserved.