1-[4-(8-hydroxy-[5]quinolylazo)-phenyl]-ethanone | 101828-51-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[4-(8-hydroxy-[5]quinolylazo)-phenyl]-ethanone
• 英文别名: 1-[4-(8-Hydroxy-[5]chinolylazo)-phenyl]-aethanon
• CAS: 101828-51-7
• 化学式: C₁₇H₁₃N₃O₂
• 分子量: 291.309
• InChiKey: GFWYFRSTSJFNNT-FMQUCBEESA-N

物化性质

• 沸点：
  548.3±45.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.56
• 重原子数：
  22.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  74.91
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  1-[4-(8-hydroxy-[5]quinolylazo)-phenyl]-ethanone 、 4-甲氧基苯甲醛 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以68%的产率得到(E)-1-(4-((E)-(8-hydroxyquinolin-5-yl)diazenyl)phenyl)-3-(4-methoxyphenyl)prop-2-en-1-one
  参考文献：
  名称：

  Synthesis, physicochemical and spectroscopic characterizations of azochalcone derivative thin films towards solar cells application

  摘要：

  A novel azochalcone derivative (ACh) has been synthesized by the reaction of azo-ketone and 4-anisaldehyde in ethanolic NaOH. The synthetized compound was characterized by FT-IR, H-1 NMR, and Mass spectra. Thin films with various thickness of ACh were deposited by thermal evaporation technique onto glass, quartz and Si wafer substrates under vacuum of 10(-5)Torr. Structural analysis of these thin films was investigated by the field emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) patterns. The optical constants such as: refractive index (n), extinction coefficient (k) and optical band gap (E-g) of pristine and annealed films have been studied in the wavelength region 200-2500 nm. Analysis of the absorption coefficient, a, spectrum shows that the most probable transition is the indirect allowed transition. The onset and fundamental optical band gaps for ACh film are found to be 2.44 and 3.37 eV, respectively. The annealing temperature changes the optical constants. Tunable structural and optical properties of ACh open up the avenue to building up the solar cell based on ACh. The electronic transport mechanisms and photovoltaic properties of the fabricated solar cell of Au/ACh/p-Si/Al have been studied. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2016.09.025
• 作为产物：
  描述：

  8-羟基喹啉 、 4-氨基苯乙酮 在 盐酸 、 sodium nitrite 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 2.0h， 以74%的产率得到1-[4-(8-hydroxy-[5]quinolylazo)-phenyl]-ethanone
  参考文献：
  名称：

  Synthesis, physicochemical and spectroscopic characterizations of azochalcone derivative thin films towards solar cells application

  摘要：

  A novel azochalcone derivative (ACh) has been synthesized by the reaction of azo-ketone and 4-anisaldehyde in ethanolic NaOH. The synthetized compound was characterized by FT-IR, H-1 NMR, and Mass spectra. Thin films with various thickness of ACh were deposited by thermal evaporation technique onto glass, quartz and Si wafer substrates under vacuum of 10(-5)Torr. Structural analysis of these thin films was investigated by the field emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD) patterns. The optical constants such as: refractive index (n), extinction coefficient (k) and optical band gap (E-g) of pristine and annealed films have been studied in the wavelength region 200-2500 nm. Analysis of the absorption coefficient, a, spectrum shows that the most probable transition is the indirect allowed transition. The onset and fundamental optical band gaps for ACh film are found to be 2.44 and 3.37 eV, respectively. The annealing temperature changes the optical constants. Tunable structural and optical properties of ACh open up the avenue to building up the solar cell based on ACh. The electronic transport mechanisms and photovoltaic properties of the fabricated solar cell of Au/ACh/p-Si/Al have been studied. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2016.09.025

文献信息

• Serrs reactive particles
  申请人：Smith Ewen William

  公开号：US20050130163A1

  公开（公告）日：2005-06-16

  The present invention relates to the provision of SERRS active polymer beads and a method of their production for use in detecting targect molecules, as well as methods of detecting target molecules.

  本发明涉及用于检测目标分子的 SERRS 活性聚合物珠及其生产方法，以及检测目标分子的方法。
• Das; Sircar, Journal of the Indian Chemical Society, 1955, vol. 32, p. 679,681,684
  作者：Das、Sircar

  DOI：——

  日期：——
• SERRS REACTIVE PARTICLES
  申请人：University of Strathclyde

  公开号：EP1521846B1

  公开（公告）日：2013-03-06