bis(methazolamidate)tetrammine nickel(II) | 146718-06-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: bis(methazolamidate)tetrammine nickel(II)
• CAS: 146718-06-1
• 化学式: C₁₀H₂₆N₁₂NiO₆S₄
• 分子量: 597.347
• InChiKey: LOLJHGPZBLHLPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 醋甲唑胺 、 氨 以 乙醇 、 氨 为溶剂， 生成 bis(methazolamidate)tetrammine nickel(II)
  参考文献：
  名称：

  Coordination behaviour of methazolamide [N(-4-methyl-2-sulfamoyl-Δ2-1,3,4-thiadiazolin-5-ylidene)] acetamide, an inhibitor of carbonic anhydrase enzyme. Synthesis, crystal structure and properties of bis(methazolamidate)tetrammine nickel(II)

  摘要：

  The interaction of methazolamide (Hmacm) with Ni(II) ion and ammonia molecules gives rise to the complex of formula [Ni(macm)2(NH3)4]. The complex crystallizes in the monoclinic P2(1)/n space group with a = 14.255(4), b = 7.126(2), c = 12.444(3) angstrom, beta = 113.12(3)-degrees and Z = 2. The structure was refined to R = 0.065 (R(w) = 0.065). The complex consists of monomeric units which interact through hydrogen bonds and van der Waals contacts. The Ni(II) ion is coordinated with the deprotonated sulfonamido nitrogen of the macm- ligand in axial sites and the ammonia molecules in equatorial positions. IR, electronic spectra and H-1 NMR results are also reported.

  DOI：

  10.1016/s0020-1693(00)81667-9