diiodocobalt;1-[2-(2-sulfanylidenepyridin-1-yl)ethyl]pyridine-2-thione | 210773-63-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: diiodocobalt;1-[2-(2-sulfanylidenepyridin-1-yl)ethyl]pyridine-2-thione
• CAS: 210773-63-0
• 化学式: C₁₂H₁₂CoI₂N₂S₂
• 分子量: 561.175
• InChiKey: WAEMZTJDZYOBBV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.55
• 重原子数：
  19.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  9.86
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  N,N'-ethylenebis(pyridin-2-thione) 、 cobalt(II) iodide 以 硝基甲烷 、 乙醇 为溶剂， 以60%的产率得到diiodocobalt;1-[2-(2-sulfanylidenepyridin-1-yl)ethyl]pyridine-2-thione
  参考文献：
  名称：

  Chain and rhomboidal “box”-like polymeric metal complexes of N′,N′-1,2-ethylenebis(pyrin-2thione)

  摘要：

  The preparations are reported of a range of complexes of Fe-II, Co-II, Ni-II, Cu-I, Ag-I; Zn and Cd with N,N'-1,2-ethylenebis(pyridin-2-thione) (EBPYT) together with relevant spectroscopic data. The compounds Co(EBPYT)Br-2 (1) and [Ni(EBPYT)(3)](ClO4)(2) . 2MeOH . MeNO2 (2) have been studied by X-ray crystallography. Compound 1 has a chain structure in which tetrahedrally coordinated cobalt centres are linked by bridging EBPYT ligands. In compound 2 octahedrally coordinated "NIS6" centres are connected by EBPYT bridges so as to form a polymeric three-dimensional array of rhomboidal "boxes". (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00029-1