Tin(II) hexafluoroacetylacetonate | 112131-28-9

• 物质功能分类: 有机原料 - 酮类化合物
• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Tin(II) hexafluoroacetylacetonate
• 英文别名: TIN (II) HEXAFLUOROACETYLACETONATE；tin(II) bis[1,3-bis(trifluoromethyl)propane-1,3-dionate]；bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tin(II)；tin(ii) bis(hexafluoroacetylacetonate)；[tin(II)(hexafluoroacetylacetonate)2]
• CAS: 112131-28-9；51319-99-4
• 化学式: C₁₀H₂F₁₂O₄Sn
• 分子量: 532.814
• InChiKey: KCGIPFBVZHIGHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

安全信息

• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38

反应信息

• 作为反应物：
  描述：

  Tin(II) hexafluoroacetylacetonate 生成 tin(IV) oxide
  参考文献：
  名称：

  Tin(ii) Hexafluoroacetylacetonate as a Precursor in Atmospheric Pressure Chemical Vapour Deposition: Synthesis, Structure and Properties

  摘要：

  A new method for the synthesis of volatile tin(II) hexafluoroacetylacetonate [Sn(C5HO2F6)(2)] was suggested, the compound was characterized by elemental analysis, IR spectroscopy, and DTA/TGA; the crystal structure was established by X-ray diffraction; the morphology and composition of the coating deposited by atmospheric pressure chemical vapour deposition were studied by SEM-EDX and XRD.

  DOI：

  10.1016/j.mencom.2012.09.003
• 作为产物：
  描述：

  tin 、 六氟乙酰丙酮 反应 24.0h， 以93%的产率得到Tin(II) hexafluoroacetylacetonate
  参考文献：
  名称：

  Tin(ii) Hexafluoroacetylacetonate as a Precursor in Atmospheric Pressure Chemical Vapour Deposition: Synthesis, Structure and Properties

  摘要：

  A new method for the synthesis of volatile tin(II) hexafluoroacetylacetonate [Sn(C5HO2F6)(2)] was suggested, the compound was characterized by elemental analysis, IR spectroscopy, and DTA/TGA; the crystal structure was established by X-ray diffraction; the morphology and composition of the coating deposited by atmospheric pressure chemical vapour deposition were studied by SEM-EDX and XRD.

  DOI：

  10.1016/j.mencom.2012.09.003

文献信息

• Derivatives of bivalent germanium, tin, and lead. Part XIX. Reactions of bis(β-ketoenolato)tin(<scp>II</scp>) compounds with metal carbonyls: the octa-carbonyldicobalt system
  作者：Anthony B. Cornwell、Philip G. Harrison

  DOI：10.1039/dt9760001608

  日期：——

  The reaction of bis(β-ketoenolato)tin(II) compounds, [SnX2], with octacarbonyldicobalt in benzene at room temperature yields products of composition [Co(CO)4}2SnX2], [Co2(CO)7(SnX2)], or [Co(CO)4(SnX)] depending on the nature of the β-ketoenolato-residue X. Infrared data indicate that the β-ketoenolato-groups chelate tin in all cases, and also the presence of both terminal and bridging carbonyl groups

  在室温下，双（β-酮烯醇）锡（II）化合物[SnX 2 ]与八羰基二钴在苯中的反应生成组成为[Co（CO）4 } 2 SnX 2 ]，[Co 2（CO）的产物7（SnX 2）]或[Co（CO）4（SnX）]取决于β-酮烯醇残基X的性质。红外数据表明，β-酮烯醇基在所有情况下都与锡螯合，并且[Co 2（CO）7（SnX 2）]中同时存在末端羰基和桥接羰基。[Co（CO）4 } 2 SnX 2的Tin-119mMössbauer数据]与[Co 2（CO）7（SnX 2）]非常相似，其结构与[Co（CO）4 } 2 Sn（pd）2 ]（pd =戊烷-2 ）所确定的结构相同。，4-dronate），表明四羰基钴基团在八面体配位的锡上占据顺式位置。[Co（CO）4（SnX）]的Mössbauer异构体位移落在3.35–3.68 mm s –1的范围内，高于相应的[SnX 2 ]化合物和涉及[Co（CO）4
• Reaction mechanism of “amine–borane route” towards Sn, Ni, Pd, Pt nanoparticles
  作者：Ortal Lidor-Shalev、David Zitoun

  DOI：10.1039/c4ra11483c

  日期：——

  Sn NPs with well-defined sizes in the range 20–100 nm have been synthesized using a chemical reduction route of metal acetylacetonate by a dimethylamine–borane Lewis complex.

  使用一种化学还原路线，通过二甲胺硼氢化物路易斯酸复合物，合成了粒径在20-100纳米范围内具有良好定义大小的Sn NPs。
• Derivatives of bivalent germanium, tin and lead. Part XXII. Palladium and platinum complexes of bivalent tin compounds
  作者：Paul F.R. Ewings、P.G. Harrison

  DOI：10.1016/s0020-1693(00)87393-4

  日期：1978.1