铵2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十三氟十二烷酸盐 | 3793-74-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 中文名称: 铵2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十三氟十二烷酸盐
• 英文名称: Azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-tricosafluorododecanoic acid
• 英文别名: azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-tricosafluorododecanoic acid
• CAS: 3793-74-6
• 化学式: C12H4F23NO2
• 分子量: 631.13
• InChiKey: CZSJYNHKKNEDDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.03
• 重原子数：
  38
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  41.1
• 氢给体数：
  1
• 氢受体数：
  25

文献信息

• PROCESS FOR PRODUCING AQUEOUS DISPERSION CONTAINING POLYTETRAFLUOROETHYLENE
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1065223A1

  公开（公告）日：2001-01-03

  An aqueous dispersion of a polytetrafluoroethylene (PTFE) is produced by using e.g. C9F19COONH4 as a surfactant. A PTFE fine powder obtained by coagulating this aqueous dispersion, is subjected to paste extrusion and stretched at a temperature of at least 250°C to obtain the porous article.

  以 C9F19COONH4 等作为表面活性剂，生产聚四氟乙烯（PTFE）的水性分散体。通过凝结这种水性分散体得到的聚四氟乙烯细粉，在至少 250°C 的温度下进行糊状挤压和拉伸，从而得到多孔制品。
• Method for absorbing and recovering fluorine-containing emulsifier
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1314700A1

  公开（公告）日：2003-05-28

  A method for adsorbing and recovering a fluorine-containing emulsifier at a high recovery from coagulation waste water of a fluoropolymer, is presented. An inorganic acid is added to coagulation waste water of a fluoropolymer containing a fluorine-containing emulsifier, to adjust the pH of the waste water to a level of at least 1 and less than 6, then a metal chloride having a solubility of at least 5 mass% in water at 25°C, or a hydrate of the metal chloride, is added to the waste water, to coagulate and remove a solid content and/or a substance convertible to a solid content, contained in the waste water, and then the waste water is contacted to a weakly basic anion exchange resin.

  本发明提出了一种从含氟聚合物的混凝废水中以高回收率吸附和回收含氟乳化剂的方法。在含有含氟乳化剂的含氟聚合物的混凝废水中加入一种无机酸，将废水的 pH 值调节到至少为 1 但小于 6 的水平，然后在 25°C 的水中加入一种溶解度至少为 5 质量％的金属氯化物或金属氯化物的水合物、或该金属氯化物的水合物，使废水中含有的固体成分和/或可转化为固体成分的物质凝结并去除，然后将废水与弱碱性阴离子交换树脂接触。
• PROCESS FOR THE RECOVERY OF FLUORINE-CONTAINING EMULSIFIERS
  申请人：Sasakura Engineering Co. Ltd.

  公开号：EP1514848A1

  公开（公告）日：2005-03-16

  An aqueous solution containing a fluorine-containing emulsifier in a low concentration of at least 1 ppm by mass and at most 1% by mass (e.g., coagulation waste water after an emulsion polymerization of a fluoropolymer and/or an aqueous solution obtained by washing with an aqueous solution a waste gas from a drying process and/or a heat treating process of the fluoropolymer) is subjected to vacuum concentration under a pressure of at most 100 kPa and a temperature of the aqueous solution of at most 100°C by means of a heating tube surface evaporation type concentrator equipped with a heat pump or the like, and the fluorine-containing emulsifier is recovered from a highly concentrated aqueous solution containing the fluorine-containing emulsifier in a higher concentration of at least 5% by mass. According to the present method, the fluorine-containing emulsifier can be recovered with a high yield from a low-concentration liquid such as coagulation waste water of a fluoropolymer.

  含有含氟乳化剂的低浓度水溶液，其质量浓度至少为 1 ppm，最多不超过 1%（例如：含氟聚合物乳液聚合后的凝结废水和/或用水溶液洗涤含氟聚合物干燥过程和/或热处理过程中产生的废气而得到的水溶液）、含氟聚合物乳液聚合后的凝结废水和/或用水溶液洗涤含氟聚合物干燥工序和/或热处理工序产生的废气后得到的水溶液），在压力不超过 100 kPa 和水溶液温度不超过 100°C 的条件下，通过配备热泵或类似装置的加热管表面蒸发型浓缩器进行真空浓缩、从高浓度水溶液中回收含氟乳化剂，高浓度含氟乳化剂的质量浓度至少为 5%。根据本方法，可从低浓度液体（如含氟聚合物的凝结废水）中高产率地回收含氟乳化剂。
• COMPOSITION, CROSSLINKED RUBBER MOLDED ARTICLE AND FLUORINE-CONTAINING POLYMER
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP3835352A1

  公开（公告）日：2021-06-16

  Provided is a composition comprising a fluorine-containing polymer and a cross-linking agent, wherein the fluorine-containing polymer comprises a vinylidene fluoride unit, a unit of a fluorine-containing monomer (1) represented by the following general formula (1):         CHX1=CX2Rf     (1) wherein one of X1 and X2 is H, the other is F, and Rf is a linear or branched fluoroalkyl group having 1 to 12 carbon atoms, and a unit of a monomer giving a crosslinking site.

  本发明提供了一种由含氟聚合物和交联剂组成的组合物，其中含氟聚合物包括一个亚氟乙烯单元、一个由以下通式（1）表示的含氟单体（1）单元： CHX1=CX2Rf (1) 其中，X1 和 X2 中的一个是 H，另一个是 F，Rf 是具有 1 至 12 个碳原子的直链或支链氟烷基，以及一个具有交联位点的单体单元。
• PERFLUOROELASTOMER COMPOSITION HAVING ENHANCED CURING PERFORMANCE
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0939785A1

  公开（公告）日：1999-09-08