di-μ-sulfido-bis[sulfido(diethyldithiocarbamato)]molybdenum(V) | 67814-43-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: di-μ-sulfido-bis[sulfido(diethyldithiocarbamato)]molybdenum(V)
• 英文别名: [Mo₂S₄(S₂CNEt₂)₂]
• CAS: 67814-43-1；36539-27-2
• 化学式: C₁₀H₂₀Mo₂N₂S₈
• 分子量: 616.69
• InChiKey: VPNYOLIXOAXARC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.61
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  di-μ-sulfido-bis[sulfido(diethyldithiocarbamato)]molybdenum(V) 、 copper(I) bromide 以 二氯甲烷 为溶剂， 以90%的产率得到[(N,N-diethyldithiocarbamate)2Mo2(μ3-S)(μ-S)3(CuBr)]
  参考文献：
  名称：

  Stepwise addition of CuBr at [(dtc)2Mo2(S)2(μ-S)2] (dtc=diethyldithiocarbamate): syntheses and crystal structures of two Mo/Cu/S clusters [(dtc)2Mo2(μ3-S)(μ-S)3(CuBr)] and [(dtc)2Mo2(μ3-S)4(CuBr)2]

  摘要：

  Reactions of [(dtc)(2)Mo-2(S)(2)(mu-S)(2)] with one or two equivalents of CuBr in CH2Cl2 afforded two new heterobimetallic sulfide clusters, [(dtc)(2)Mo-2(mu(3)-S)(mu-S)(3)(CuBr)] (1) and [(dtc)(2)Mo-2(mu(3)-S)(4)(CuBr)(2)] (2). Both compounds were characterized by elemental analysis, IR, UV-vis and X-ray analysis. Compound I contains a butterfly-shaped Mo2S4Cu core in which one CuBr unit is coordinated by one bridging S and two terminal S atoms of the [(dtc)(2)Mo-2(S)(2)(mu-S)(2)] moiety. In the structure of 2, one [(dtc)(2)Mo-2(S)(2)(mu-S)(2)] moiety and two CuBr units are held together by Six Cu-mu(3)-S bonds, forming a cubane-like Mo2S4Cu2 core. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.08.026
• 作为产物：
  描述：

  sodium diethyldithiocarbamate trihydrate 、 ammonium di-μ-disulfido-tetrakis[disulfido]dimolybdenum(V) 以 甲醇 为溶剂， 以80%的产率得到di-μ-sulfido-bis[sulfido(diethyldithiocarbamato)]molybdenum(V)
  参考文献：
  名称：

  Coyle Lee; Halbert; Pan, Inorganica Chimica Acta, 1996, vol. 243, # 1-2, p. 147 - 160

  摘要：

  DOI：

文献信息

• Development of the Rational Synthetic Routes towards Trinuclear and Cubane-type Tetranuclear Mixed-metal Sulfido Clusters Containing Noble Metals.
  作者：Tomotake IKADA、Yasushi MIZOBE、Shigeki KUWATA、Masanobu HIDAI

  DOI：10.1246/nikkashi.2001.493

  日期：——

  モリブデンおよびタングステンのスルフィド架橋二核錯体[M2S2(μ2–S)2(S2CNEt2)2] (M = Mo，W)と各種貴金属錯体とを反応させることにより，[M′(μ2–S)2M2(μ2–S)2] (M = Mo : M′ = Pt; M = W : M′ = Pd, Pt)，[M′(μ3–S)(μ2–S)3M2] (M = Mo, W : M′ = Rh, Ir)，および[M′2M2(μ3–S)4] (M = Mo : M′ = Pd; M = Mo, W : M′ = Rh, Ir)骨格を有する一連の三核およびキュバン型四核混合金属クラスターを，それぞれ選択的に合成できることを見いだした．これらの反応においてどの骨格構造が生成するかは，用いる金属の組み合わせ，または導入する金属錯体上の配位子の種類に大きく依存することが判明した．一連の新規なクラスターの構造については，[Pt(PPh3)(μ2–S)2W(S2CNEt2)}2(μ2–S)2]，[Pd(PPh3)}2Mo(S2CNEt2)}2(μ3–S)4], [Ir(PPh3)2(μ3–S)(μ2–S)3W(S2CNEt2)}2(μ2–Cl)]，[Rh(cod)}2MoCl(S2CNEt2)}2(μ3–S)4] (cod = 1,5-cyclooctadiene)，および[(RuCp*)2MoCl(S2CNEt2)}2(μ3–S)4](Cp* = η5–C5Me5)の単結晶X線解析を行って確認した．

  通过将二氟化钼和钨的硫化物桥联二核络合物[M2S2(μ2–S)2(S2CNEt2)2] (M = Mo，W)与各种贵金属络合物反应，发现能够选择性合成一系列具有骨架结构的三核和立方体型四核混合金属簇，[M′(μ2–S)2M2(μ2–S)2] (M = Mo : M′ = Pt; M = W : M′ = Pd, Pt)，[M′(μ3–S)(μ2–S)3M2] (M = Mo, W : M′ = Rh, Ir)，以及[M′2M2(μ3–S)4] (M = Mo : M′ = Pd; M = Mo, W : M′ = Rh, Ir)。这些反应中生成何种骨架结构主要依赖于所用金属的组合或引入金属络合物上的配体种类。对一系列新型簇的结构进行了单晶X射线解析，包括[Pt(PPh3)(μ2–S)2W(S2CNEt2)}2(μ2–S)2]，[Pd(PPh3)}2Mo(S2CNEt2)}2(μ3–S)4]，[Ir(PPh3)2(μ3–S)(μ2–S)3W(S2CNEt2)}2(μ2–Cl)]，[Rh(cod)}2MoCl(S2CNEt2)}2(μ3–S)4] (cod = 1,5-环辛二烯)，以及[(RuCp*)2MoCl(S2CNEt2)}2(μ3–S)4](Cp* = η5–C5Me5)。
• 2D MATERIALS
  申请人：The University of Manchester

  公开号：US20180258117A1

  公开（公告）日：2018-09-13

  The synthesis of 2D metal chalcogenide nanosheets and metal-ion or metalloid-ion doped 2D metal chalcogenide nanosheets by adding a metal complex to a hot dispersing medium. The mean lateral dimension of the nanosheets may be controlled by appropriate temperature selection.

  通过向热分散介质中添加金属配合物，可以合成2D金属硫族化合物纳米片和金属离子或金属类离子掺杂的2D金属硫族化合物纳米片。通过适当的温度选择，可以控制纳米片的平均横向尺寸。
• Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Incomplete Cubane-Type M₂M‘S₄ and Cubane-Type M₂M‘₂S₄ Cores (M = Mo, W; M‘ = Rh, Ir)
  作者：Tomotake Ikada、Shigeki Kuwata、Yasushi Mizobe、Masanobu Hidai

  DOI：10.1021/ic981035r

  日期：1999.1.1

  The reactions of sulfido-bridged dimolybdenum and ditungsten complexes [M2S2(mu(2)-S)(2)(S2CNEt2)(2)] (1; M = Mo, W) with an equimolar amount of [M'Cl(PPh3)(3)] (M' = Rh, Ir) gave a series of mixed-metal incomplete cubane-type sulfide clusters [M'(PPh3)(2)(mu(3)-S)(mu 2-S)(3)M(S2CNEt2)}(2)(mu(2)-Cl)]. On the other hand, mixed-metal cubane-type sulfide clusters [M'(cod)}(2)MCl(S2CNEt2)}(2)(mu(3)-S)(4)] (M' = Rh, Ir; cod = 1,5-cyclooctadiene) were obtained by the reactions of 1 with an equimolar amount of [M'Cl(cod)](2). Detailed structures of [Ir(PPh3)(2)(mu(3)-S)(mu(2)-S)(3)W(S2CNEt2)}2(mu(2)-Cl)]. 2CH(2)Cl(2) (3b . 2CH(2)Cl(2)) and [Rh(cod)}(2)MoCl(S2CNEt2)}(2)(mu(3)-S)(4)]. 0.5CH(2)Cl(2) (4a . 0.5CH(2)Cl(2)) have been determined by X-ray crystallography. Compound 3b . 2CH(2)Cl(2) crystallized in the monoclinic system, space group P2(1)/n, With a 10.521(4) Angstrom, b = 32.325(5) Angstrom, c = 17.277(3) Angstrom, beta = 96.34(2)degrees, and Z = 4. Refinement by full-matrix least-squares techniques gave final residuals R = 0.071 and R-w = 0.068. Compound 4a . 0.5CH(2)Cl(2) crystallized in the monoclinic system, space group P2(1)/c, with a = 32.990(3) Angstrom, b = 10.847(4) Angstrom, c = 26.312(4) Angstrom, beta = 111.274(8)degrees, and Z = 8. Refinement by full-matrix least-squares techniques gave final residuals R = 0.037 and R-w = 0.048.
• Mo2S42+ core: new syntheses, new complexes, and electrochemical diversity
  作者：Kenneth F. Miller、Alice E. Bruce、James L. Corbin、Scot Wherland、Edward I. Stiefel

  DOI：10.1021/ja00535a050

  日期：1980.7
• Preparation, characterization and cyclic voltammetric behaviour of dimeric sulphidomolybdenum(V) dithiocarbamate complexes
  作者：K.S. Nagaraja、M.R. Udupa

  DOI：10.1016/s0277-5387(00)86677-2

  日期：1985.1