(η5-C5Me5)2WO | 115795-92-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (η5-C5Me5)2WO
• CAS: 115795-92-1
• 化学式: C₂₀H₃₀OW
• 分子量: 470.308
• InChiKey: IQGHELUNIIXJEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.82
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (η5-C5Me5)2WO 在 glycol 作用下， 以 氘代苯 为溶剂， 生成 (η5-pentamethylcyclopentadienyl)2W(η2-O,O-glycolate)
  参考文献：
  名称：

  双（五甲基环戊二烯基）钨（IV）的卤化物，氢化物，烷基，氧代及相关衍生物

  摘要：

  DOI：

  10.1016/s0277-5387(00)80724-x
• 作为产物：
  描述：

  {(η5-pentamethylcyclopentadienyl)2WOH}{BF4} 在 KOH 作用下， 以 四氢呋喃 、 水 为溶剂， 以48%的产率得到(η5-C5Me5)2WO
  参考文献：
  名称：

  双（五甲基环戊二烯基）钨（IV）的卤化物，氢化物，烷基，氧代及相关衍生物

  摘要：

  DOI：

  10.1016/s0277-5387(00)80724-x

文献信息

• Bis(η-pentamethylcyclopentadienyl) complexes of molybdenum, tungsten and rhenium via metal vapour synthesis
  作者：F. Geoffrey N. Cloke、Jeremy P. Day、Jennifer C. Green、Christopher P. Morley、Anthony C. Swain

  DOI：10.1039/dt9910000789

  日期：——

  Co-condensation of molybdenum or tungsten atoms with 1,2,3,4,5-pentamethylcyclopenta-1,3-diene (C5HMe5) affords the decamethylmetallocene dihydrides [M(eta-C5Me5)2H2] (M = Mo or W). UV photolysis of the latter results in the sequential formation of the 'tucked-in' compounds [M(eta-C5Me5) (eta-6-C5Me4CH2)H] and [M(eta-C5Me5)eta-7-C5Me3(CH2)2}] (M = Mo or W). For the tungsten analogue, deuterium labelling studies show that the latter reaction proceeds via the decamethylmetallocene followed by intramolecular oxidative addition to a ring methyl group. Treatment of [W(eta-C5Me5)2H2] with CCI4 yields [W(eta-C5Me5)2CI2], which reacts with ZnMe2 to afford [W(eta-C5Me5)2Me2] and with LiCH2Bu(t) to afford [W(eta-C5Me5) (eta-6-C5Me4CH2)Cl]. Reduction of [W(eta-C5Me5)2Cl2] with sodium amalgam gives [W(eta-C5Me5) (eta-6-C5Me4CH2)H]; reduction of the latter with potassium affords an intermediate anion, which reacts with water or iodomethane to give [W(eta-C5Me5)2H2] or [W(eta-C5Me5)2Me2] respectively. [Mo(eta-C5Me5)2H2] reacts with 1,2-diiodoethane to give [Mo(eta-C5Me5)2I2], which is reduced by sodium amalgam to [Mo(eta-C5Me5)(eta-C5Me4CH2)H]; there is no evidence for the formation of [Mo(eta-C5Me5)2}2]. Co-condensation of rhenium atoms with C5HMe5 yields [Re(eta-C5Me5)2H] and [Re(eta-C5Me5)(eta-6-C5Me4CH2], both of which can be reversibly protonated to give [Re(eta-C5Me5)2H2]+ and [Re(eta-C5Me5)(eta-6-C5Me4CH2)H]+ respectively. UV photolysis of [Re(eta-C5Me5)2H] gives the stable 17-electron metallocene [Re(eta-C5Me5)2], which reacts with nitric oxide to afford the bent nitrosyl derivative, [Re(eta-C5Me5)2(NO)]. [Re(eta-C5Me5)2] may be reduced to the diamagnetic anion [Re(eta-C5Me5)2]- with potassium; the latter reacts with iodomethane to afford [Re(eta-C5Me5)2CH3], but the analogous reaction with chloro- or iodo-methyl ether results in the unexpected formation of [Re(eta-C5Me5)eta-CH2OMe)}Me]. Oxidation of [Re(eta-C5Me5)2] with AgBF4 gives the 'tucked-in' cation [Re(eta-C5Me5)(eta-6-C5Me4CH2)H]+, which is also obtained from the reaction of [Re(eta-C5Me5)2H] with chlorocarbons. UV photolysis of [Re(eta-C5Me5)(eta-6-C5Me4CH2)H]+ gives the doubly 'tucked-in' cation [Re(eta-C5Me5)eta-7-C5Me3(CH2)2}]+; photolysis of [Re(eta-C5Me5)2H2]+ also results in the stepwise formation of [Re(eta-C5Me5)(eta-6-C5Me4CH2)H]+ and [Re(eta-C5Me5)eta-7-C5Me3(CH2)2}]+.
• Elimination processes for alkyl, hydride, and hydroxy derivatives of permethyltungstenocene
  作者：Gerard Parkin、John E. Bercaw

  DOI：10.1021/om00107a008

  日期：1989.5
• Yoon, Myungok; Tyler, David R., Chemical Communications, 1997, # 6, p. 639 - 640
  作者：Yoon, Myungok、Tyler, David R.

  DOI：——

  日期：——
• Parkin, Gerard; Marsh, Richard E.; Schaefer, William P., Inorganic Chemistry, 1988, vol. 27, # 18, p. 3262 - 3264
  作者：Parkin, Gerard、Marsh, Richard E.、Schaefer, William P.、Bercaw, John E.

  DOI：——

  日期：——