[(Z)-22-hydroxydocos-9-enyl] 3-hydroxypropanoate | 284493-15-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: [(Z)-22-hydroxydocos-9-enyl] 3-hydroxypropanoate
• CAS: 284493-15-8
• 化学式: C₂₅H₄₈O₄
• 分子量: 412.654
• InChiKey: SYZQZPFYVZWHRX-XQRVVYSFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  29
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [(Z)-22-hydroxydocos-9-enyl] 3-hydroxypropanoate 在 palladium on activated charcoal sodium hydroxide 、 氢气 作用下， 以 甲醇 为溶剂， 70.0 ℃ 、101.33 kPa 条件下， 反应 0.5h， 生成 L,22-二十二碳二醇
  参考文献：
  名称：

  Bruchins—Mitogenic 3-(Hydroxypropanoyl) Esters of Long Chain Diols from Weevils of the Bruchidae

  摘要：

  Mono- and bis 3-(hydroxypropanoyl) esters of long chain, unsaturated diols have been isolated and identified from two genera of the family Bruchidae, and have been shown to be responsible for the mitogenic activity observed on pea pods resulting from oviposition by the pea weevil, Bruchus pisorum. The mitogenic compounds have been characterized and synthesized. Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(00)00650-5
• 作为产物：
  描述：

  9-癸炔-1-醇 在 Lindlar's catalyst 吡啶 、 正丁基锂 、 三氟化硼乙醚 、 氢气 、 对甲苯磺酸 、 sodium iodide 作用下， 以 四氢呋喃 、 甲醇 、 六甲基磷酰三胺 、 正己烷 、 二氯甲烷 、 苯 为溶剂， 反应 7.25h， 生成 [(Z)-22-hydroxydocos-9-enyl] 3-hydroxypropanoate
  参考文献：
  名称：

  Bruchins—Mitogenic 3-(Hydroxypropanoyl) Esters of Long Chain Diols from Weevils of the Bruchidae

  摘要：

  Mono- and bis 3-(hydroxypropanoyl) esters of long chain, unsaturated diols have been isolated and identified from two genera of the family Bruchidae, and have been shown to be responsible for the mitogenic activity observed on pea pods resulting from oviposition by the pea weevil, Bruchus pisorum. The mitogenic compounds have been characterized and synthesized. Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(00)00650-5

文献信息

• Bruchins—Mitogenic 3-(Hydroxypropanoyl) Esters of Long Chain Diols from Weevils of the Bruchidae
  作者：James E Oliver、Robert P Doss、R.Thomas Williamson、John R Carney、E.David DeVilbiss

  DOI：10.1016/s0040-4020(00)00650-5

  日期：2000.9

  Mono- and bis 3-(hydroxypropanoyl) esters of long chain, unsaturated diols have been isolated and identified from two genera of the family Bruchidae, and have been shown to be responsible for the mitogenic activity observed on pea pods resulting from oviposition by the pea weevil, Bruchus pisorum. The mitogenic compounds have been characterized and synthesized. Published by Elsevier Science Ltd.