2-methyl-8-(2,3,4,5-tetramethyl-1,3-cyclopentadienyl)-1,2,3,4-tetrahydroquinoline | 1003295-02-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-methyl-8-(2,3,4,5-tetramethyl-1,3-cyclopentadienyl)-1,2,3,4-tetrahydroquinoline
• 英文别名: 2-Methyl-8-(2,3,4,5-tetramethylcyclopenta-1,3-dien-1-yl)-1,2,3,4-tetrahydroquinoline
• CAS: 1003295-02-0
• 化学式: C₁₉H₂₅N
• 分子量: 267.414
• InChiKey: YGMYXSXLCNCDQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,2,3,4-四氢喹哪啶 以51%的产率得到2-methyl-8-(2,3,4,5-tetramethyl-1,3-cyclopentadienyl)-1,2,3,4-tetrahydroquinoline
  参考文献：
  名称：

  METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES

  摘要：

  本发明提供了一种新型过渡金属配合物，其中配位了一个含有氨基基团的单环戊二烯基配体，以及一种合成该配合物的方法，以及使用该配合物进行烯烃聚合的方法。根据本发明的制备过渡金属配合物的方法包括通过使用含有保护基团的化合物阻止氮原子的副反应的步骤，因此可以以较高的产率简单地制备过渡金属配合物。此外，根据本发明的过渡金属配合物具有一个五角环结构，其中通过苯桥连接的氨基基团在金属位点附近形成了一个稳定的键，因此，立体单体可以轻松接近过渡金属配合物。当应用含有过渡金属配合物的催化剂组合物在乙烯和具有较大立体位阻的单体的共聚合中时，可以制备出密度小于0.910g/cc的超低密度聚烯烃共聚物，除了具有高分子量和线性低密度的聚烯烃外，反应性也非常高。

  公开号：

  US20100062927A1

文献信息

• METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARED USING THE METOD, CATALYST COMPOSITION CONTAINING THE COMPLEXES
  申请人：LEE Choong-Hoon

  公开号：US20110172451A1

  公开（公告）日：2011-07-14

  The present invention provides a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.

  本发明提供了一种新型过渡金属配合物，其中配位了一个含有氨基团的单环戊二烯基配体，以及一种合成该配合物的方法，以及使用该配合物进行烯烃聚合的方法。根据本发明的制备过渡金属配合物的方法包括通过使用含有保护基团的化合物阻止氮原子的副反应的步骤，因此可以以更简单的方式高产率地制备过渡金属配合物。此外，根据本发明的过渡金属配合物具有一个五角形环结构，其中通过苯桥连接的氨基团与金属位点附近形成了稳定的键，因此，立体构型的单体可以轻松接近过渡金属配合物。
• Transition Metal Complex, Catalyst Composition Including the Same and Olefin Polymer Using Catalyst Composition
  申请人：Lee Choong Hoon

  公开号：US20070225158A1

  公开（公告）日：2007-09-27

  Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a catalyst composition including the same, and an olefin polymer using the catalyst composition. The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex. By using a catalyst composition including the transition metal complex, a linear low density polyolefin copolymer having a high molecular weight and a very low density polyolefin copolymer having a density of 0.910 g/cc or less can be produced in a polymerization of monomers having large steric hindrance. Further, the reactivity for the olefin monomer having large steric hindrance is excellent.

  提供了一种新型过渡金属配合物，其中包括一个含有氨基基团的单环戊二烯基配体，一个包括该配合物的催化剂组合物，以及使用该催化剂组合物的烯烃聚合物。该过渡金属配合物具有一个五边形环结构，其中通过苯基桥连接的氨基基团与金属位点附近形成稳定键，因此，立体位阻单体可以轻松接近该过渡金属配合物。通过使用包括该过渡金属配合物的催化剂组合物，在聚合具有较大立体位阻的单体时，可以生产具有高分子量的线性低密度聚烯烃共聚物和密度为0.910克/立方厘米或更低的超低密度聚烯烃共聚物。此外，对于具有较大立体位阻的烯烃单体，其反应性非常优秀。
• METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARE USING THE METHOD, CATALYTS COMPOSITION CONTAINING THE COMPLEXES
  申请人：Lee Choong-Hoon

  公开号：US20100062927A1

  公开（公告）日：2010-03-11

  The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex. When a catalyst composition comprising the transition metal complex is applied in copoly-merization of ethylene and monomers having large steric hindrance, a very low density polyolefin copolymer having a density of less than 0.910 g/cc, in addition to a polyolefin having a high molecular weight and a linear low density, can be prepared. Furthermore, the reactivity is also very high.

  本发明提供了一种新型过渡金属配合物，其中配位了一个含有氨基基团的单环戊二烯基配体，以及一种合成该配合物的方法，以及使用该配合物进行烯烃聚合的方法。根据本发明的制备过渡金属配合物的方法包括通过使用含有保护基团的化合物阻止氮原子的副反应的步骤，因此可以以较高的产率简单地制备过渡金属配合物。此外，根据本发明的过渡金属配合物具有一个五角环结构，其中通过苯桥连接的氨基基团在金属位点附近形成了一个稳定的键，因此，立体单体可以轻松接近过渡金属配合物。当应用含有过渡金属配合物的催化剂组合物在乙烯和具有较大立体位阻的单体的共聚合中时，可以制备出密度小于0.910g/cc的超低密度聚烯烃共聚物，除了具有高分子量和线性低密度的聚烯烃外，反应性也非常高。
• METHOD FOR PREPARING TRANSITION METAL COMPLEXES, TRANSITION METAL COMPLEXES PREPARED USING THE METHOD, CATALYST COMPOSITION CONTAINING THE COMPLEXES
  申请人：LEE Choong-Hoon

  公开号：US20110177935A1

  公开（公告）日：2011-07-21

  The present invention provides a novel transition metal complex where a monocy-clopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.

  本发明提供了一种新型的过渡金属配合物，其中配位了引入了酰胺基团的单环戊二烯基配体，以及制备该配合物的方法和使用该配合物的烯烃聚合方法。根据本发明的制备过渡金属配合物的方法包括使用含有保护基的化合物阻止氮原子的副反应，因此可以以高收率更简单地制备过渡金属配合物。此外，本发明的过渡金属配合物具有五边形环结构，其中通过苯基桥连接的酰胺基团在金属位点附近形成稳定的键，因此，立体单体可以轻易地接近过渡金属配合物。
• US7928256B2
  申请人：——

  公开号：US7928256B2

  公开（公告）日：2011-04-19