9,10-bis(2-hydroxyphenyl)anthracene | 910244-07-4

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9,10-bis(2-hydroxyphenyl)anthracene
• 英文别名: 9,10-di(2-hydroxyphenyl)anthracene；2-[10-(2-hydroxyphenyl)anthracen-9-yl]phenol
• CAS: 910244-07-4
• 化学式: C₂₆H₁₈O₂
• 分子量: 362.428
• InChiKey: AHPDOFFCLXXLRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis(2-hydroxyphenyl)anthracene 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Photo Physical Properties of 9,10-Bis(hydroxyphenyl)anthracene Derivatives

  摘要：

  Among the most promising fluorescent materials for sensor applications, anthracene and its derivatives have been widely studied. In this contribution, the synthesis and characterization of a series of isomers of bis(hydroxyphenyl)anthracene derivatives are described. The preparation of the corresponding derivatives via Suzuki cross-coupling reactions is presented with particular emphasis on finding appropriate protecting groups and studying the influence of the position of the hydroxy group on the outcome of the reaction. Moreover, the effects of protonation and deprotonation on absorption and emission spectra are reported and correlated to semi-empirical quantum mechanical calculations.

  DOI：

  10.1007/s00706-007-0625-2
• 作为产物：
  描述：

  蒽醌 在 正丁基锂 、 三溴化硼 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 为溶剂， 反应 65.0h， 生成 9,10-bis(2-hydroxyphenyl)anthracene
  参考文献：
  名称：

  Synthesis and Photo Physical Properties of 9,10-Bis(hydroxyphenyl)anthracene Derivatives

  摘要：

  Among the most promising fluorescent materials for sensor applications, anthracene and its derivatives have been widely studied. In this contribution, the synthesis and characterization of a series of isomers of bis(hydroxyphenyl)anthracene derivatives are described. The preparation of the corresponding derivatives via Suzuki cross-coupling reactions is presented with particular emphasis on finding appropriate protecting groups and studying the influence of the position of the hydroxy group on the outcome of the reaction. Moreover, the effects of protonation and deprotonation on absorption and emission spectra are reported and correlated to semi-empirical quantum mechanical calculations.

  DOI：

  10.1007/s00706-007-0625-2

文献信息

• Novel Materials For Organic Electroluminescent Devices
  申请人：Stoessel Philipp

  公开号：US20080171225A1

  公开（公告）日：2008-07-17

  The present invention relates to novel materials which can be used in organic electronic devices, in particular electroluminescent devices, and are derivatives of fused aromatic systems.

  本发明涉及一种可以用于有机电子器件，特别是电致发光器件的新型材料，它们是融合芳香系统的衍生物。
• Alkylation-, Heating-, and Doping-Induced Emission Enhancement of a Polyaromatic Tube in the Solid State
  作者：Kiyonori Kuroda、Masafumi Otsuki、Kohei Yazaki、Yoshihisa Sei、Munetaka Akita、Michito Yoshizawa

  DOI：10.1002/asia.201800034

  日期：2018.3.2

  facile exterior alkylation of the polyaromatic framework leads to a moderately fluorescent tube (R=‐OC10H21; ΦF=20 %) in the solid state. The emission intensity of the solid‐state alkyl‐substituted tube is remarkably enhanced upon heating (up to 1.6 times, ΦF=31 %) as well as doping with fluorescent dyes (up to 4.2 times, ΦF=83 %) through efficient energy transfer.

  作为关键步骤，通过对二苯蒽衍生物进行立体控制的环三聚反应，以克为单位有效地制备了具有亚纳米级腔的聚芳烃管。聚芳族框架引线的外部容易烷基化以适度荧光管（R = -OC 10 ħ 21 ; Φ ˚F = 20％）在固态下。固态烷基取代的管的发光强度在加热时显着地提高（高达1.6倍，Φ ˚F = 31％），以及用荧光染料掺杂（高达4.2倍，Φ ˚F = 83％）通过高效能量转移。
• An anthracene-containing bistable [2]rotaxane featuring color and fluorescence changes
  作者：Wei Zhou、Ying Wu、Bao-Qi Zhai、Qiao-Chun Wang、Da-Hui Qu

  DOI：10.1039/c3ra46517a

  日期：——

  We report an anthracene-containing bistable [2]rotaxane that can respond to the acidic/basic reagents, the change of the solvent polarity, and the counteranions, etc. The movement can generate remarkable, high-contrast fluorescent intensity change, along with an obvious color change.

  我们报告了一种含蒽的双稳态[2]轮烷，它可以对酸性/碱性试剂、溶剂极性的改变以及反离子等做出反应。这种运动能产生显著的、高对比度的荧光强度变化，同时还能产生明显的颜色变化。
• Materials for organic electroluminescent devices
  申请人：Merck Patent GmbH

  公开号：US08124249B2

  公开（公告）日：2012-02-28

  The present invention relates to novel materials which can be used in organic electronic devices, in particular electroluminescent devices, and are derivatives of fused aromatic systems.

  本发明涉及一种新型材料，可用于有机电子器件，特别是电致发光器件，并且是融合芳香系统的衍生物。
• NEUE MATERIALIEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN
  申请人：Merck Patent GmbH

  公开号：EP1859005A1

  公开（公告）日：2007-11-28