(acetylmethyl)mercury chloride | 6704-27-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (acetylmethyl)mercury chloride
• 英文别名: Chlormercuri-aceton；1-Chlormercurio-propanon；α-Chlorquecksilberaceton；Chlorquecksilberaceton；2-Oxo-propylquecksilber(1+); Chlorid；2-oxo-propylmercury (1+); chloride；chloro-(2-oxo-propyl)-mercury；Chloromercurio-aceton；[Hg(acetonyl)Cl]；chloro-mercuri-acetone
• CAS: 6704-27-4
• 化学式: C₃H₅ClHgO
• 分子量: 293.115
• InChiKey: NPZKGIMPCUETOK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.23
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (acetylmethyl)mercury chloride 在 吡啶 、 硫化氢 、 三氯化磷 作用下， 生成 Triisopropenylphosphit
  参考文献：
  名称：

  Lutsenko,I.F.; Kraits,Z.S., Journal of general chemistry of the USSR, 1962, vol. 32, p. 1645 - 1647

  摘要：

  DOI：
• 作为产物：
  描述：

  2-丁氧基丙烯 、 mercury(II) diacetate 在 potassium chloride 、 水 作用下， 生成 (acetylmethyl)mercury chloride
  参考文献：
  名称：

  Nessmejanow; Luzenko; Wereschtschagina, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1947, p. 67

  摘要：

  DOI：

文献信息

• Process for the preparation of halogeno-mercuri-aldehydes and -ketones
  申请人：Societe Nationale des Poudres et Explosifs

  公开号：US04242280A1

  公开（公告）日：1980-12-30

  The invention relates to a process for the preparation of halogeno-mercuri-aldehydes and -ketones. According to the invention, an alkenyl ester is reacted with a mercuric halide in the presence of water and, preferably, of an acid acceptor. The reaction, which is preferably carried out at between 15.degree. and 35.degree. C., makes it possible to obtain very pure products with excellent yields, especially when mercuric oxide is used as the acid acceptor.

  该发明涉及一种制备卤代汞醛和酮的过程。根据该发明，烯基酯与汞卤化物在水的存在下，并且最好在酸受体的存在下反应。该反应最好在15度至35度之间进行，可以获得非常纯净的产品，收率非常高，尤其是当汞氧化物用作酸受体时。
• The First Family of Platinum(IV) Acetonyl Complexes. Mono-, Bis-, and Tris(acetonyl) Derivatives
  作者：José Vicente、Aurelia Arcas、Jesús M. Fernández-Hernández、Delia Bautista

  DOI：10.1021/om0605027

  日期：2006.8.1

  as the Me4N salt (2·NMe4) by reacting [HgCH2C(O)Me}2] and K[PtCl3(C2H4)] (1:2) in the presence of an excess of (Me4N)Cl. The tris(acetonyl) Pt(IV) complexes fac-(PPN)2[PtCH2C(O)Me}3Cl3] (3), fac-[PtCH2C(O)Me}3(Cl)L2] (L = tBuNC (4), XyNC (5; Xy = C6H3Me2-2,6)), and fac-[PtCH2C(O)Me}3Cl(N∧N)] (N∧N = bpy (6), phen (7)) have been obtained by reacting 1·K with (PPN)Cl, L, and N∧N, respectively, and

  [Hg CH 2 C（O）Me} 2 ]与K [PtCl 3（C 2 H 4）]反应（2：1摩尔比），得到K [Pt 2 CH 2 C（O）Me}} 6（ μ-Cl）的3 ]（1 ·K）通过中间K [铂CH 2 C（O）Me}氯2（η 2 -CH 2 CH 2）]（2 ·K）。通过使1 ·K与18-crown-6和2反应，还可以得到[K（18-C-6）] +盐（1 ·C）的阴离子络合物1。通过在存在下使[Hg CH 2 C（O）Me} 2 ]和K [PtCl 3（C 2 H 4）]（1：2）反应分离为Me 4 N盐（2 ·NMe 4）过量的（Me 4 N）Cl。三（丙酮酰基）Pt（IV）配合物fac-（PPN）2 [Pt CH 2 C（O）Me} 3 Cl 3 ]（3），fac- [Pt CH 2 C（O）Me} 3（ Cl）L 2 ]（L = t BuNC（4），XyNC（5
• Acetonyl Platinum(II) Complexes
  作者：José Vicente、Aurelia Arcas、Jesús M. Fernández-Hernández、Gabriel Aullón、Delia Bautista

  DOI：10.1021/om700665n

  日期：2007.12.1

  Me4N[PtCH2C(O)Me}Cl-2(eta(2)-C2H4)] (1), reacts either (1) with neutral ligands to afford cis-Me4N[PtCH2C(O)Me}Cl-2(L)] (L = CO (2), eta(2)-PhCH=CH2 (3), eta(2)-PhC CPh (4), eta(2)-H2C=C=CMe2 (5), PPh3 (6), AsPh3 (7)), trans- or/and cis- [PtCH2C(O)Me}ClL2] (L = PPh3 (8), AsPh3 (9), tht (10), XyNC (11), 'BuNC (12), py (17)), [PtCH2C(O)Me}Cl(eta(2)-C2H4)(L)] (L = py (16)), or cis-[PtCH2C(O)Me}-ClL2] (L-2 = norbornadiene (nbd, 18), 1,5-cyclooctadiene (cod, 19), bis(diphenylphosphino)methane (dppm, 20), 4,4'-di-tert-butyl-2,2'-bipyridyl (dbbpy, 21)) or (2) with [Tl(acac)] to give [PtCH2C(O)Me}(O,O-acac)(eta(2)-C2H4)] (22) which reacts with neutral ligands to give [PtCH2C(O)Me}(O,O-acac)(L)] (L = CO (23), PPh3 (24), XyNC (25)). The different behavior of py and stronger :pi-acceptor ligands, as CO and PR3 toward 1, has been explained through a DFT study. Reaction of 11trans with 2 equiv of XyNC affords a mixture of trans-[PtC(O)NHXy}Cl(CNXy)(2)] (13) and trans-[PtC(NHXy)(2)}Cl(CNXy)(2)]Cl (14). The first was isolated by recrystallization and the latter by reacting cis-[PtCl2(CNXy)(2)] with 2 equiv of XyNC. However, cis-[PtCH2C(O)Me}(2)(bpy)] reacts with 4 equiv of XyNC to give cis-[PtCH2C(O)Me}(2)(CNXy)(2)] (15).
• Three-component radical condensations involving benzoylmethyl radicals, alkenes, and diphenyl disulfide
  作者：Glen A. Russell、Shekhar V. Kulkarni

  DOI：10.1021/jo00062a008

  日期：1993.5

  Acyl-substituted methyl radicals (RCOCH2.; R = H, Me, Ph), generated by photolysis of RCOCH2-HgCl, add to alkenes, enol ethers, or vinyl sulfides to give adduct radicals that are readily trapped by PhSSPh to yield a three-component condensation product. The presence of an alkali metal carbonate is crucial in preventing side reactions resulting in the conversion of the mercurial to RCOCH3 by PhSH formed in the photolysis.
• Lutsenko,I.F.; Kraits,Z.S., Doklady Chemistry, 1960, vol. 135, p. 1371 - 1373
  作者：Lutsenko,I.F.、Kraits,Z.S.

  DOI：——

  日期：——