| 1431294-20-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1431294-20-0
• 化学式: C₂₄H₁₆BClF₂N₄
• 分子量: 444.679
• InChiKey: SLKWGHNYKWZBES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-氨基喹啉 、 4,4-difluoro-3,5-dichloro-8-phenyl-4-bora-3a,4a-diaza-s-indacene 以 乙腈 为溶剂， 反应 72.0h， 以60%的产率得到
  参考文献：
  名称：

  A highly selective copper fluorescent indicator based on aminoquinoline substituted BODIPY

  摘要：

  A highly selective fluorescent indicator for copper, substituted with an aminoquinoline group at the position 3 or 5 of the BODIPY has been synthesized. The indicator has very low fluorescence quantum yield in acetonitrile with emission maxima at 580 nm. Upon binding copper it shows 50 nm bathochromic shifts with a change of solution color and a large increase in the fluorescence intensity. The fluorescence lifetime in acetonitrile was too short and could not be determined; whereas fluorescence decay profile of the copper complex was described by a, mono-exponential decay with the lifetime of 4.38 ns. ESI-MS enabled detection of a Cu center dot 1 CN complexes which was fromed by C-C bond cleavage of acetonitrile. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.02.013

文献信息

• A highly selective copper fluorescent indicator based on aminoquinoline substituted BODIPY
  作者：Xu Jia、Xiaoting Yu、Xiaolong Yang、Jie Cui、Xiaoliang Tang、Weisheng Liu、Wenwu Qin

  DOI：10.1016/j.dyepig.2013.02.013

  日期：2013.8

  A highly selective fluorescent indicator for copper, substituted with an aminoquinoline group at the position 3 or 5 of the BODIPY has been synthesized. The indicator has very low fluorescence quantum yield in acetonitrile with emission maxima at 580 nm. Upon binding copper it shows 50 nm bathochromic shifts with a change of solution color and a large increase in the fluorescence intensity. The fluorescence lifetime in acetonitrile was too short and could not be determined; whereas fluorescence decay profile of the copper complex was described by a, mono-exponential decay with the lifetime of 4.38 ns. ESI-MS enabled detection of a Cu center dot 1 CN complexes which was fromed by C-C bond cleavage of acetonitrile. (C) 2013 Elsevier Ltd. All rights reserved.