(2,5-Dihydroxyphenyl)-pyridin-3-ylmethanone | 937640-15-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2,5-Dihydroxyphenyl)-pyridin-3-ylmethanone
• CAS: 937640-15-8
• 化学式: C₁₂H₉NO₃
• 分子量: 215.208
• InChiKey: UYUUWJVIFCXTTI-UHFFFAOYSA-N

物化性质

• 沸点：
  431.9±35.0 °C(Predicted)
• 密度：
  1.365±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70.4
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-吡啶甲醛 、 对苯醌 以 苯 为溶剂， 反应 30.0h， 以72%的产率得到(2,5-Dihydroxyphenyl)-pyridin-3-ylmethanone
  参考文献：
  名称：

  The solar-chemical photo-Friedel–Crafts heteroacylation of 1,4-quinones

  摘要：

  Photochemical reactions between 1,4-benzo- and 1,4-naphthoquinone and several heteroaromatic carbaldehydes were investigated under solar irradiation conditions. These reactions gave the corresponding heteroacylated hydroquinones in the range 71%-92% yield. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.11.149

文献信息

• The solar-chemical photo-Friedel–Crafts heteroacylation of 1,4-quinones
  作者：Julio Benites、David Rios、Pilar Díaz、Jaime A. Valderrama

  DOI：10.1016/j.tetlet.2010.11.149

  日期：2011.2

  Photochemical reactions between 1,4-benzo- and 1,4-naphthoquinone and several heteroaromatic carbaldehydes were investigated under solar irradiation conditions. These reactions gave the corresponding heteroacylated hydroquinones in the range 71%-92% yield. (C) 2010 Elsevier Ltd. All rights reserved.