Monodeuterio-Keten | 60032-17-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Monodeuterio-Keten
• 英文别名: Deuteroketene
• CAS: 60032-17-9
• 化学式: C₂H₂O
• 分子量: 43.0293
• InChiKey: CCGKOQOJPYTBIH-MICDWDOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  LEDA HPLC丙酮 、 丙酮 在 nickel-chromium-iron 作用下， 生成 Monodeuterio-Keten
  参考文献：
  名称：

  The Microwave Spectrum of Ketene

  摘要：

  The microwave absorption spectra of the ketene molecules H21C212O16, H1D2C212O16, and D22C212O16 have been investigated. Reciprocal moments of inertia have been determined for each from the measurements. The centrifugal distortion theory of Hillger and Strandberg has been found valid for both Q and R branches. The structure has been calculated and dipole moment measured; results check and extend the accuracy of values previously determined by other methods. Intensities of satellites of the lightest molecule corresponding to the lowest three vibrational fundamentals have also been measured and changes in the average reciprocal moments determined. The vibrational frequencies have been calculated and found different from values reported in the literature by infrared workers. References and suggestions for further work are given.

  DOI：

  10.1063/1.1700517

文献信息

• The Microwave Spectrum of Ketene
  作者：H. R. Johnson、M. W. P. Strandberg

  DOI：10.1063/1.1700517

  日期：1952.4

  The microwave absorption spectra of the ketene molecules H21C212O16, H1D2C212O16, and D22C212O16 have been investigated. Reciprocal moments of inertia have been determined for each from the measurements. The centrifugal distortion theory of Hillger and Strandberg has been found valid for both Q and R branches. The structure has been calculated and dipole moment measured; results check and extend the accuracy of values previously determined by other methods. Intensities of satellites of the lightest molecule corresponding to the lowest three vibrational fundamentals have also been measured and changes in the average reciprocal moments determined. The vibrational frequencies have been calculated and found different from values reported in the literature by infrared workers. References and suggestions for further work are given.