1,4-di-(N-vinylformamido)butane | 1313373-90-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,4-di-(N-vinylformamido)butane
• 英文别名: N-ethenyl-N-[4-[ethenyl(formyl)amino]butyl]formamide
• CAS: 1313373-90-8
• 化学式: C₁₀H₁₆N₂O₂
• 分子量: 196.249
• InChiKey: BVJDNYHEFKLTCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  白消安 、 N-乙烯基甲酰胺 在 potassium tert-butylate 、 叔丁基邻苯二酚 作用下， 以 甲基叔丁基醚 为溶剂， 生成 1,4-di-(N-vinylformamido)butane
  参考文献：
  名称：

  [EN] POLYMERS PREPARED FROM MIXTURES OF MULTIFUNCTIONAL N-VINYLFORMAMIDE AND HYBRID REACTIVE N-VINYLFORMAMIDE CROSSLINKING MONOMER MOIETIES AND USES THEREOF
  [FR] POLYMÈRES PRÉPARÉS À PARTIR DE MÉLANGES DE FRAGMENTS MONOMÈRES DE RÉTICULATION N-VINYLFORMAMIDE MULTIFONCTIONNELS ET N-VINYLFORMAMIDE RÉACTIFS HYBRIDES ET LEURS UTILISATIONS

  摘要：

  本发明提供了由至少一种反应性乙烯单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一种反应性乙烯单体基团和具有至少一种N-乙烯基甲酰胺功能性和至少一种其他反应性乙烯功能性的混合N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一种具有一种N-乙烯基甲酰胺功能性和至少一种其他反应性非乙烯功能性的混合反应性N-乙烯基甲酰胺单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；以及由至少一种具有一种N-乙烯基甲酰胺功能性和至少一种其他反应性非乙烯功能性的混合反应性N-乙烯基甲酰胺单体基团和具有至少一种N-乙烯基甲酰胺功能性和至少一种其他反应性乙烯功能性的混合N-乙烃基甲酰胺交联基团聚合而成的聚合物。该发明还提供了包含新型交联聚合物的各种组合物。

  公开号：

  WO2011084993A1

文献信息

• POLYMERS PREPARED FROM MIXTURES OF MULTIFUNCTIONAL N-VINYLFORMAMIDE AND HYBRID REACTIVE N-VINYLFORMAMIDE CROSSLINKING MONOMER MOIETIES AND USES THEREOF
  申请人：Musa Osama M.

  公开号：US20110166308A1

  公开（公告）日：2011-07-07

  The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality. The invention further provides a wide variety of compositions comprising the novel crosslinked polymers.

  本发明提供了由至少一个反应性乙烯单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一个反应性乙烯单体基团和具有至少一个N-乙烯基甲酰胺功能和至少一个其他反应性乙烯基团的混合型N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一个混合型反应性N-乙烯基甲酰胺单体基团（具有一个N-乙烯基甲酰胺功能和至少一个其他反应性非乙烯基团）和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；以及由至少一个混合型反应性N-乙烯基甲酰胺单体基团（具有一个N-乙烯基甲酰胺功能和至少一个其他反应性非乙烯基团）和具有至少一个N-乙烯基甲酰胺功能和至少一个其他反应性乙烯基团的混合型N-乙烯基甲酰胺交联基团聚合而成的聚合物。此外，本发明还提供了包含新型交联聚合物的各种组合物。
• Liquid absorption agent
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0473881A1

  公开（公告）日：1992-03-11

  A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: wherein R1, R2, and R3 independently represent a hydrogen atom or methyl; X represents a group -COOY, wherein Y represents a hydrogen atom, an alkali metal, Ci - C6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group -CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R3 is methyl, X is not cyano, 2-ketopyrrolidinyl, lower alkoxy, lower alkylcarbonyl, lower alkoxycarbonyl and lower alkyl substituted with sulfonic acid or a salt thereof; M represents a hydrogen atom or an alkali metal; p represents 0 or 1; and a molar ratio of m:n is 50 - 100 : 50 - 0.

  一种用于水或有机溶剂的液体吸收剂，其主要成分是一种交联的 N-乙烯基羧酸酰胺树脂，该树脂的骨架链包括用交联剂交联的下式所示重复单元的均聚物或共聚物： 其中 R1、R2 和 R3 分别代表氢原子或甲基； X代表基团-COOY，其中Y代表氢原子、碱金属、Ci-C6烷基或被羟基、二烷基氨基或季铵基取代的低级烷基；代表基团-CONHZ，其中Z代表氢原子或被二烷基氨基、季铵基、磺酸或其碱金属盐取代的低级烷基；氰基、2-酮基吡咯烷基、低级烷氧基、低级酰基、低级酰氧基或被磺酸或其碱金属盐取代的低级烷基，但当 R3 为甲基时，X 不是氰基、2-酮基吡咯烷基、低级烷氧基、低级烷羰基、低级烷氧羰基和被磺酸或其盐取代的低级烷基； M 代表氢原子或碱金属； p 代表 0 或 1；以及 m:n 的摩尔比为 50 - 100 : 50 - 0。
• Use of fine particulate crosslinked type n-vinylamide resin microgel
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0510246A1

  公开（公告）日：1992-10-28

  A fine particulate crosslinked type N-vinylcarboxylic acid amide resin having an average particle size of 10 µm or less comprising backbone chains of a homopolymer or copolymer comprising repeating units (A) or (A) and (B) of the formulae: wherein R¹, R² and R³ each independently represent a hydrogen atom or methyl group; X represents a group -COOY, wherein Y represents a hydrogen atom, an alkali metal, a C₁ - C₁₈ alkyl group or a lower alkyl group substituted with hydroxyl group, a dialkylamino group or a quaternary ammonium group; a group -CONHZ, wherein Z represents a hydrogen atom or a lower alkyl group substituted with a dialkylamino group, a quaternary ammonium group, a sulfonic acid or an alkali metal salt thereof; a cyano group, a 2-ketopyrroridinyl group, a lower alkoxy group, a lower acyl group, a lower alkoxycarbonyl group or a lower alkyl group substituted with sulfonic acid or an alkali metal salt thereof; M represents a hydrogen atom, an alkali metal or an ammonium group, with proviso that when R³ is a methyl group, X is not a cyano group, a 2-ketopyrrolidinyl group, a lower alkoxy group, a lower acyl group, a lower alkoxycarbonyl group and a lower alkyl group substituted with sulfonic acid or an alkali metal salt thereof, p represents 0 or 1, and the molar ratio of m:n represents 30 - 100:70 - 0.

  一种细颗粒交联型 N-乙烯基羧酸酰胺树脂，其平均粒径为 10 微米或更小，由均聚物或共聚物的骨架链组成，均聚物或共聚物包括式中的重复单元(A)或(A)和(B)： 其中 R¹、R² 和 R³ 各自独立地代表氢原子或甲基； X 代表基团-COOY，其中 Y 代表氢原子、碱金属、C₁-C₁₈ 烷基或被羟基、二烷基氨基或季铵基取代的低级烷基；基团-CONHZ，其中 Z 代表氢原子或被二烷基氨基、季铵基、磺酸或其碱金属盐取代的低级烷基；氰基、2-酮基吡咯烷基、低级烷氧基、低级酰基、低级烷氧羰基或被磺酸或其碱金属盐取代的低级烷基；M 代表氢原子、碱金属或铵基团，但当 R³ 为甲基时，X 不是氰基、2-酮基吡咯烷基、低级烷氧基、低级酰基、低级烷氧基羰基和被磺酸或其碱金属盐取代的低级烷基；p 代表 0 或 1，m：n 的摩尔比为 30 - 100:70 - 0。
• Polyoxymethylene resin composition
  申请人：——

  公开号：US20020183430A1

  公开（公告）日：2002-12-05

  A polyoxymethylene resin composition, which comprises (A) 100 parts by weight of polyoxymethylene resin, (B) 0.01 to 5 parts by weight of at least one polymer selected from homopolymers of N-vinylcarboxylic acid amides and copolymers of N-vinylcarboxylic acid amides and other vinyl monomers, and (C) 0.01 to 5 parts by weight of at least one compound selected from the group consisting of polyalkylene glycol and its derivatives, fatty acid amides, esters of alcohols and fatty acids, and esters of alcohols and dicarboxylic acids. Such a polyoxymethylene resin composition has a small amount of released formaldehyde gas during production and molding and suppressed scorching generation and is also distinguished in the water resistance and repeated impact resistance of the resulting moldings.

  一种聚甲醛树脂组合物，它包括(A)100 份（按重量计）聚甲醛树脂，(B)0.01 至 5 份（按重量计）至少一种选自 N-乙烯基羧酸酰胺均聚物和 N-乙烯基羧酸酰胺与其他乙烯基单体共聚物的聚合物，以及(C)0.0.01 至 5 重量份的至少一种化合物，该化合物选自由聚亚烷基二醇及其衍生物、 脂肪酸酰胺、醇和脂肪酸的酯以及醇和二羧酸的酯组成的组。这样的聚甲醛树脂组合物在生产和成型过程中释放的甲醛气体量少，焦烧的产生受到抑制，所制成的成型品的耐水性和耐反复冲击性也很出色。
• Fine particulate cross-linked type N-vinylamide resin
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0859015B1

  公开（公告）日：2001-06-27