2-(11-Hydroxyundecyloxy)benzaldehyd | 320722-51-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-(11-Hydroxyundecyloxy)benzaldehyd
• 英文别名: 2-(11-hydroxyundecoxy)benzaldehyde
• CAS: 320722-51-8
• 化学式: C₁₈H₂₈O₃
• 分子量: 292.419
• InChiKey: HSXSLHARFNHZMY-UHFFFAOYSA-N

物化性质

• 沸点：
  434.3±15.0 °C(Predicted)
• 密度：
  1.016±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  21.0
• 可旋转键数：
  13.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  46.53
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  2-(11-Hydroxyundecyloxy)benzaldehyd 在 三乙胺 、 三氟乙酸 、 PEG 400 作用下， 以 二氯甲烷 为溶剂， 生成 2,8,12,18-tetrahexyl-5,15-bis[2-(11-thioacetyl-undecyloxy)-phenyl]-3,7,13,17-tetramethyl porphyrin
  参考文献：
  名称：

  Disulfide-Strapped Porphyrins for Monolayer Formation on Gold

  摘要：

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.

  DOI：

  10.1021/ol006615i
• 作为产物：
  描述：

  11-溴-1-十一醇 、 水杨醛 在 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 72.0h， 以83%的产率得到2-(11-Hydroxyundecyloxy)benzaldehyd
  参考文献：
  名称：

  Disulfide-Strapped Porphyrins for Monolayer Formation on Gold

  摘要：

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.

  DOI：

  10.1021/ol006615i

文献信息

• Brokatzky-Geiger, Juergen; Eberbach, Wolfgang, Chemische Berichte, 1984, vol. 117, # 6, p. 2157 - 2192
  作者：Brokatzky-Geiger, Juergen、Eberbach, Wolfgang

  DOI：——

  日期：——
• BROKATZKY-GEIGER, J.;EBERBACH, W., CHEM. BER., 1984, 117, N 6, 2157-2192
  作者：BROKATZKY-GEIGER, J.、EBERBACH, W.

  DOI：——

  日期：——
• Disulfide-Strapped Porphyrins for Monolayer Formation on Gold
  作者：James E. Redman、Jeremy K. M. Sanders

  DOI：10.1021/ol006615i

  日期：2000.12.1

  [GRAPHICS]Porphyrins with a disulfide-containing strap have been prepared as an alternative to dithiols for self-assembled monolayer formation on gold surfaces. The strapped porphyrins have the advantage of greater air stability than their dithiol analogues. Cis and trans atropisomers of a strapped porphyrin were isolated. Gold electrodes modified with dithiol and disulfide porphyrins were not identical as evidenced by contact angle or electrochemical measurements.