5-(dithiolan-3-yl)-N-[2-(2,2,2-trifluoroacetyl)phenyl]pentanamide | 1034136-39-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(dithiolan-3-yl)-N-[2-(2,2,2-trifluoroacetyl)phenyl]pentanamide
• CAS: 1034136-39-4
• 化学式: C₁₆H₁₈F₃NO₂S₂
• 分子量: 377.452
• InChiKey: XWHPHCDJGHUCTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  96.8
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  1-(2-氨基苯基)-2,2,2-三氟乙烷酮 、 Thioctic acid 在 草酰氯 、 potassium carbonate 作用下， 以 二氯甲烷 、 四氢呋喃 为溶剂， 反应 51.0h， 生成 5-(dithiolan-3-yl)-N-[2-(2,2,2-trifluoroacetyl)phenyl]pentanamide
  参考文献：
  名称：

  Selective recognition of fumarate from maleate with a gold nanoparticle-based colorimetric sensing system

  摘要：

  A colorimetric sensing system of gold nanoparticles functionalized with carboxylate-binding units of o-(trifluoroacetyl)carboxanilide is described, which selectively recognizes a trans-dicarboxylate (fumarate) from its cis-isomer (maleate) and several dicarboxylates through inter-particle cross-linking, resulting in an apparent color change from red to purple. (C) 2008 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2008.03.142

文献信息

• Selective recognition of fumarate from maleate with a gold nanoparticle-based colorimetric sensing system
  作者：Kyung-Seog Youk、Kyung Mi Kim、Amrita Chatterjee、Kyo Han Ahn

  DOI：10.1016/j.tetlet.2008.03.142

  日期：2008.5

  A colorimetric sensing system of gold nanoparticles functionalized with carboxylate-binding units of o-(trifluoroacetyl)carboxanilide is described, which selectively recognizes a trans-dicarboxylate (fumarate) from its cis-isomer (maleate) and several dicarboxylates through inter-particle cross-linking, resulting in an apparent color change from red to purple. (C) 2008 Published by Elsevier Ltd.