mercury(II) trichloroacetate | 15873-63-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: mercury(II) trichloroacetate
• 英文别名: (CCl3COO)2mercury(II)；mercuric trichloroacetate；Bis-trichloracetoxy-quecksilber(II)；mercury(2+);2,2,2-trichloroacetate
• CAS: 15873-63-9；20464-21-5
• 化学式: 2C₂Cl₃O₂*Hg
• 分子量: 525.35
• InChiKey: YAXFHYZSWFOBMO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  40.13
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  、 mercury(II) trichloroacetate 以 甲醇 、 丙酮 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis, Characterisation and Reactivity of Phenylmercury(II) Compounds Containing Hg-S Bonds

  摘要：

  DOI：

  10.1080/00945719809351687
• 作为产物：
  描述：

  mercury(II) oxide 、 三氯乙酸 在 calcium carbonate 作用下， 以 甲醇 为溶剂， 以99%的产率得到mercury(II) trichloroacetate
  参考文献：
  名称：

  Mercury(II) Trichloroacetate. Part I. Formation, Stabilization, Isolation and Decomposition

  摘要：

  The formation, isolation and decomposition of mercury(II) trichloroacetate is described. The reaction between mercury(II) oxide and trichloroacetic acid is conducted in methanolic solution. In this manner the new salt, mercury(II) trichloroacetate, is isolated. Also, the intermediate of its decomposition, mercury(I) trichloroacetate, may be isolated.

  DOI：

  10.1080/00945719708000165
• 作为试剂：
  描述：

  在 甲醇 、 sodium hydroxide 、 sodium tetrahydroborate 、 mercury(II) trichloroacetate 、 sodium carbonate 作用下， 生成 ethoxycarbonylamino-oxahomobrendanone
  参考文献：
  名称：

  Inokuma, Shun; Sugie, Akihiko; Moriguchi, Koichi, Heterocycles, 1982, vol. 19, # 8, p. 1419 - 1426

  摘要：

  DOI：

文献信息

• Stereochemistry of addition of mercury salts to alkynes
  作者：V. R. Kartashov、T. N. Sokolova、Yu. K. Grishin、N. V. Malisova、N. S. Zefirov

  DOI：10.1007/bf02495613

  日期：1998.8

  the length of the acyl substituent.syn-Addition also occurs in the acetoxymercuration ofm-chlorophenyl(methyl)acetylene and 1-methoxybut-2-yne; in the latter case, this route predominates. The stereochemistry of the reaction can also depend on the ratio of the reactants. It is proposed that the reaction occurs by several schemes in which these factors manifest themselves in different degrees.

  Hg(OOCR)2（R=Et、Prn、Pri 和 Bun）与甲基苯乙炔（使用相应的酸作为溶剂）反应得到顺式和反式加合物的混合物。顺式加合物的数量随着酰基取代基长度的增加而增加。syn-加成也发生在间氯苯基（甲基）乙炔和1-甲氧基丁-2-炔的乙酰氧基汞化反应中；在后一种情况下，这条路线占主导地位。反应的立体化学还取决于反应物的比例。建议通过几种方案发生反应，其中这些因素在不同程度上表现出来。
• 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane—efficient reagent for the synthesis of 1-substituted silatranes
  作者：Yu. I. Bolgova、E. N. Timofeeva、A. I. Albanov、O. M. Trofimova、N. F. Chernov

  DOI：10.1134/s1070428017070272

  日期：2017.7

  The reaction of silatrane HSi(OCH2CH2)3N with mercury(II) salts HgX2 (X = OCOMe, OCOCF3, OCOCCl3, SCN, Br) afforded the corresponding 1-substituted silatranes XSi(OCH2CH2)3N in good yields.

  甲硅烷基HSi（OCH 2 CH 2）3 N与汞（II）盐HgX 2（X = OCOMe，OCOCF 3，OCOCCl 3，SCN，Br）的反应得到相应的1-取代的硅杂环戊烷XSi（OCH 2 CH 2）3 N高产。
• Mercury(II) Trichloroacetate. Part II. Formation and Use as a Versatile Reagent in Ferrocene Chemistry
  作者：Alberto Federman Neto、Aurea Donizete Lanchote Borges、Ivan Pérsio de Arruda Campos、Joseph Miller

  DOI：10.1080/00945719708003158

  日期：1997.11

  The preparation of a methanolic solution of mercury(II) trichloroacetate is described. This reagent is used in an improved decamercuration of ferrocene. Decamercurated ferrocene is converted to decahaloferrocenes and used as the starting material in a new method for the synthesis of decadeuteroferrocene.
• Synthesis, Characterisation and Reactivity of Phenylmercury(II) Compounds Containing Hg-S Bonds
  作者：S. K. Srivastava、Sharmila Jain、S. B. Saxena

  DOI：10.1080/00945719809351687

  日期：1998.10
• Mercury(II) Trichloroacetate. Part I. Formation, Stabilization, Isolation and Decomposition
  作者：Alberto Federman Neto、Aurea Donizete Lanchote Borges、Ivan Pérsio de Arruda Campos、Joseph Miller

  DOI：10.1080/00945719708000165

  日期：1997.10

  The formation, isolation and decomposition of mercury(II) trichloroacetate is described. The reaction between mercury(II) oxide and trichloroacetic acid is conducted in methanolic solution. In this manner the new salt, mercury(II) trichloroacetate, is isolated. Also, the intermediate of its decomposition, mercury(I) trichloroacetate, may be isolated.