ethylenediammonium galactarate | 709038-77-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethylenediammonium galactarate
• 英文别名: 2-azaniumylethylazanium;(2S,3R,4S,5R)-2,3,4,5-tetrahydroxyhexanedioate
• CAS: 709038-77-7
• 化学式: C₂H₈N₂*C₆H₁₀O₈
• 分子量: 270.24
• InChiKey: IDWNBAUQLYPGRW-UEXKISHTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -8.6
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  217
• 氢给体数：
  6
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  ethylenediammonium galactarate 在 甲醇 、 乙酰氯 、 三乙胺 作用下， 以 甲醇 为溶剂， 反应 20.0h， 以1.39 g的产率得到
  参考文献：
  名称：

  Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

  摘要：

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

  DOI：

  10.1080/07328300903080749
• 作为产物：
  描述：

  meso-galactaric acid 、 乙二胺 以 水 为溶剂， 反应 20.0h， 以81%的产率得到ethylenediammonium galactarate
  参考文献：
  名称：

  Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

  摘要：

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

  DOI：

  10.1080/07328300903080749

文献信息

• Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates
  作者：Donald E. Kiely、Arvind Vishwanathan、Bevan P. Jarman、Merilyn Manley-Harris

  DOI：10.1080/07328300903080749

  日期：2009.7.29

  Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.