2,6-dibromo-9,10-bis(4-butylphenyl)anthracene | 1372406-27-3

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2,6-dibromo-9,10-bis(4-butylphenyl)anthracene
• 英文别名: 2,6-Dibromo-9,10-bis(4-butylphenyl)anthracene
• CAS: 1372406-27-3
• 化学式: C₃₄H₃₂Br₂
• 分子量: 600.436
• InChiKey: WTTHGHWDHYPOOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,6-dibromo-9,10-bis(4-butylphenyl)anthracene 、 4-methyl-N-(4-(9-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)fluoren-9-yl)phenyl)-N-(p-tolyl)aniline 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 48.0h， 以31.7%的产率得到
  参考文献：
  名称：

  Noncrystalline blue-emitting 9,10-diphenylanthracene end-capped with triphenylamine-substituted fluorene

  摘要：

  Two blue-emitting oligomers, namely FDPA1 and FDPA2 containing 9,10-diphenylanthracene core end-capped with triphenylamine-substituted fluorene has been synthesized and characterized. The Spiro-configuration end-capping groups imparts two compounds with pronounced morphological stability (T-g > 185 degrees C, T-d > 420 degrees C) and excellent hole injection ability (E-HOMO > -5.27 eV) with the advantageous optical characteristics of corresponding core. Scanning electron microscope (SEM) and X-ray diffraction (XRD) reveal that the two oligomers form excellent amorphous films and possess good morphological stability after annealing. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2011.11.003
• 作为产物：
  描述：

  2,6-Dibromo-9,10-bis(4-butylphenyl)anthracene-9,10-diol 在 hypophosphorous acid sodium salt 、 potassium iodide 作用下， 以 溶剂黄146 为溶剂， 反应 3.0h， 以0.92 g的产率得到2,6-dibromo-9,10-bis(4-butylphenyl)anthracene
  参考文献：
  名称：

  Noncrystalline blue-emitting 9,10-diphenylanthracene end-capped with triphenylamine-substituted fluorene

  摘要：

  Two blue-emitting oligomers, namely FDPA1 and FDPA2 containing 9,10-diphenylanthracene core end-capped with triphenylamine-substituted fluorene has been synthesized and characterized. The Spiro-configuration end-capping groups imparts two compounds with pronounced morphological stability (T-g > 185 degrees C, T-d > 420 degrees C) and excellent hole injection ability (E-HOMO > -5.27 eV) with the advantageous optical characteristics of corresponding core. Scanning electron microscope (SEM) and X-ray diffraction (XRD) reveal that the two oligomers form excellent amorphous films and possess good morphological stability after annealing. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2011.11.003

文献信息

• Noncrystalline blue-emitting 9,10-diphenylanthracene end-capped with triphenylamine-substituted fluorene
  作者：Yujian Zhang、Yanxian Jin、Ru Bai、Zhenwei Yu、Bin Hu、Mi Ouyang、Jingwei Sun、Chunhui Yu、Junlei Liu、Cheng Zhang

  DOI：10.1016/j.jphotochem.2011.11.003

  日期：2012.1

  Two blue-emitting oligomers, namely FDPA1 and FDPA2 containing 9,10-diphenylanthracene core end-capped with triphenylamine-substituted fluorene has been synthesized and characterized. The Spiro-configuration end-capping groups imparts two compounds with pronounced morphological stability (T-g > 185 degrees C, T-d > 420 degrees C) and excellent hole injection ability (E-HOMO > -5.27 eV) with the advantageous optical characteristics of corresponding core. Scanning electron microscope (SEM) and X-ray diffraction (XRD) reveal that the two oligomers form excellent amorphous films and possess good morphological stability after annealing. (C) 2011 Elsevier B.V. All rights reserved.