9-溴-10-[1,1':3',1''-三联苯]-5'-基蒽 | 474688-74-9

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 中文名称: 9-溴-10-[1,1':3',1''-三联苯]-5'-基蒽
• 中文别名: 9-溴-10-(1,1':3',1''-三联苯-5'-基)蒽；10-(3,5-二苯基苯基)-9-溴蒽；1-(3,5-二苯基苯基)-9-溴蒽
• 英文名称: 9-bromo-10-(3,5-terphenyl)-anthracene
• 英文别名: 9-bromo-10-(3,5-diphenylphenyl)anthracene；9-(3,5-Diphenylphenyl)-10-bromoanthracene
• CAS: 474688-74-9
• 化学式: C₃₂H₂₁Br
• 分子量: 485.423
• InChiKey: BQYDXENQXPPQLP-UHFFFAOYSA-N

物化性质

• 沸点：
  612.6±24.0 °C(Predicted)
• 密度：
  1.312±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  9-溴-10-[1,1':3',1''-三联苯]-5'-基蒽 在 四(三苯基膦)钯 、 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 水 为溶剂， 反应 25.5h， 生成
  参考文献：
  名称：

  有机化合物、混合物、组合物及有机电子器件

  摘要：

  本申请公开了一种有机化合物、混合物、组合物及有机电子器件。有机化合物具有如通式(1)所示的结构。本申请的有机化合物能够提高蓝光荧光有机电子器件发光效率及寿命。

  公开号：

  CN115504949A
• 作为产物：
  描述：

  9-(3,5-二苯基苯基)蒽 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 DMF (N,N-dimethyl-formamide) 为溶剂， 以90%的产率得到9-溴-10-[1,1':3',1''-三联苯]-5'-基蒽
  参考文献：
  名称：

  EP1496041

  摘要：

  公开号：

文献信息

• Double-spiro organic compounds and organic electroluminescent devices using the same
  申请人：LG Chem, Ltd.

  公开号：US06998487B2

  公开（公告）日：2006-02-14

  Disclosed are double-spiro organic compounds and an organic electroluminescence (EL) device using the same. The double-spiro organic compounds are configured to have at least three planar and substantially linear moieties, such that one planar moiety is located between two neighboring planar moieties and that the intervening planar moiety shares an atom with each of the two neighboring planar moieties. The double-spiro compounds generally have high melting point above about 300 degree C. and low crystallinity, which provide thermal stability to the organic EL devices. These organic compounds have good sublimability. They also have light-emitting, hole-injecting, hole-transporting, electron injection, electron-transporting properties and characteristics, which are favorable in the organic EL devices.

  揭示了双螺环有机化合物及其使用的有机电致发光（EL）器件。这些双螺环有机化合物被设计为至少具有三个平面且基本线性的基团，使得一个平面基团位于两个相邻的平面基团之间，并且介于两个相邻平面基团之间的中间基团与这两个相邻的平面基团中的每一个共享一个原子。双螺环化合物通常具有高于约300摄氏度的高熔点和低结晶度，这为有机EL器件提供了热稳定性。这些有机化合物具有良好的升华性能。它们还具有发光、注入正空穴、正空穴传输、注入电子、电子传输性能和特性，在有机EL器件中具有优势。
• Novel aromatic compound and organic electroluminescent element containing the same
  申请人：Ikeda Hidetsugu

  公开号：US20050214565A1

  公开（公告）日：2005-09-29

  A novel aromatic compound having an anthracene skeleton structure and an asymmetric molecular structure; and an organic electroluminescence device which comprises a cathode, an anode and an organic thin film layer comprising at least one layer containing a light emitting layer and sandwiched between the cathode and the anode in which at least one layer in the organic thin film layer contains the above novel aromatic compound singly or as a component of a mixture. The organic electroluminescence device exhibits a great luminance of emitted light, a great efficiency of light emission and a high purity of color, emits bluish light, is excellent in stability at high temperatures and has a long life. The organic electroluminescence device can be provided by utilizing the novel aromatic compound.

  一种具有蒽骨架结构和不对称分子结构的新型芳香化合物；以及一种有阴极、阳极和有机薄膜层的有机电致发光装置，该有机薄膜层至少包含一个包含发光层的层，并夹在阴极和阳极之间，其中有机薄膜层中的至少一层单独或作为混合物成分包含上述新型芳香化合物。该有机电致发光装置显示出发射光的大亮度、高效率的发光和高纯度的颜色，发出蓝色光，高温稳定性优异且寿命长。可以利用该新型芳香化合物提供有机电致发光装置。
• Aromatic compound and organic electroluminescent element containing the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US07790892B2

  公开（公告）日：2010-09-07

  A novel aromatic compound having an anthracene skeleton structure and an asymmetric molecular structure; and an organic electroluminescence device which comprises a cathode, an anode and an organic thin film layer comprising at least one layer containing a light emitting layer and sandwiched between the cathode and the anode in which at least one layer in the organic thin film layer contains the above novel aromatic compound singly or as a component of a mixture. The organic electroluminescence device exhibits a great luminance of emitted light, a great efficiency of light emission and a high purity of color, emits bluish light, is excellent in stability at high temperatures and has a long life. The organic electroluminescence device can be provided by utilizing the novel aromatic compound.

  一种具有蒽骨架结构和不对称分子结构的新型芳香化合物；以及一种有阴极、阳极和有机薄膜层的有机电致发光装置，其中至少包含一个发光层的层并夹在阴极和阳极之间，有机薄膜层中的至少一层单独或作为混合物的组分含有上述新型芳香化合物。该有机电致发光装置具有发射光的大亮度、高效率和高纯度的颜色，发出蓝色光，高温稳定性优异且寿命长。通过利用新型芳香化合物可以提供有机电致发光装置。
• NOVEL AROMATIC COMPOUND AND ORGANIC ELECTROLUMINESCNET ELEMENT CONTAINING THE SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1496041A1

  公开（公告）日：2005-01-12

  A novel aromatic compound having an anthracene skeleton structure and an asymmetric molecular structure; and an organic electroluminescence device which comprises a cathode, an anode and an organic thin film layer comprising at least one layer containing a light emitting layer and sandwiched between the cathode and the anode in which at least one layer in the organic thin film layer contains the above novel aromatic compound singly or as a component of a mixture. The organic electroluminescence device exhibits a great luminance of emitted light, a great efficiency of light emission and a high purity of color, emits bluish light, is excellent in stability at high temperatures and has a long life. The organic electroluminescence device can be provided by utilizing the novel aromatic compound.

  一种具有蒽骨架结构和不对称分子结构的新型芳香族化合物；以及一种有机电致发光器件，该器件包括一个阴极、一个阳极和一个有机薄膜层，该有机薄膜层至少包含一层发光层并夹在阴极和阳极之间，其中有机薄膜层中至少有一层单独含有上述新型芳香族化合物或作为混合物的组分。这种有机电致发光器件的发光亮度高、发光效率高、颜色纯度高，能发出蓝光，在高温下稳定性好，使用寿命长。利用新型芳香族化合物可以提供有机电致发光器件。
• Compound and organic electronic device using the same
  申请人：NICHEM FINE TECHNOLOGY CO., LTD.

  公开号：US11038123B2

  公开（公告）日：2021-06-15

  Provided are a novel compound and an organic electronic device using the same. The novel compound is represented by the following Formula (I): wherein n1, n2, m1, m2, m3, and g1 are each independently an integral, and the sum of n1 and n2 is 2 or 3; Ant is L1, L2 and L3 are each independently an arylene group; G1 and G2 are each independently selected from the group consisting of: a hydrogen atom, a deuterium atom, an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, a heterocycloalkyl group, an aryl group, and a heteroaryl group; and R1 and R2 are each independently selected from the group consisting of: a hydrogen atom, a deuterium atom, an alkyl group, and an aryl group.

  本文提供了一种新型化合物和使用该化合物的有机电子设备。该新型化合物由下式（I）表示： 其中 n1、n2、m1、m2、m3 和 g1 各自独立地为一个积分，且 n1 和 n2 之和为 2 或 3； Ant 为 L1、L2 和 L3 各自独立地为芳烯基；G1 和 G2 各自独立地选自由氢原子、氘原子、烷基、烯基、炔基、环烷基、杂环烷基、芳基和杂芳基组成的组；以及 R1 和 R2 各自独立地选自由氢原子、氘原子、烷基和芳基组成的组。