fisetinidin | 7762-00-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: fisetinidin
• 英文别名: cyanidin；2-(3,4-dihydroxy-phenyl)-3,7-dihydroxy-chromenylium；7.3.3'.4'-Tetrahydroxyflavylium；2-(3,4-Dihydroxyphenyl)chromenylium-3,7-diol
• CAS: 7762-00-7
• 化学式: C₁₅H₁₁O₅
• 分子量: 271.249
• InChiKey: ZBGITCYVOHVJEB-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  cyanidin 3-O-[2-O-(2-O-(4-O-(6-O-(4-O-(β-glucopyranosyl)-trans-caffeoyl)-β-glucopyranosyl)-trans-caffeoyl)-β-glucopyranosyl)-6-O-(trans-caffeoyl)-β-glucopyranoside]-5-O-[6-O-(malonyl)-β-glucopyranoside] 在 盐酸 、 水 作用下， 反应 1.0h， 生成 fisetinidin 、 丙二酸 、 TRANS-咖啡酸
  参考文献：
  名称：

  A tetra-acylated cyanidin 3-sophoroside-5-glucoside from the purple-violet flowers of Moricandia arvensis (L.) DC. (Brassicaceae)

  摘要：

  A novel tetra-acylated cyanidin 3-sophoroside-5-glucoside was isolated from the purple-violet flowers of Moricandia arvensis (L.) DC. (Family: Brassicaceae), and determined to be cyanidin 3-O-[2-O-(2-O-(4-O-(6-O-(4-O-(beta-glucopyranosyl)-trans-caffeoyl)-beta-glucopyranosyl)-trans-caffeoyl)-beta-glucopyranosyl)-6-O-(trans-caffeoyl)-beta-glucopyranoside]-5-O-[ 6-O-(malonyl)-beta-glucopyranoside] by chemical and spectroscopic methods. (C) 2013 Phytochemical Society of Europe. Published by Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.phytol.2012.12.007

文献信息

• A tetra-acylated cyanidin 3-sophoroside-5-glucoside from the purple-violet flowers of Moricandia arvensis (L.) DC. (Brassicaceae)
  作者：Fumi Tatsuzawa、Shun Ito、Motoki Sato、Hiroki Muraoka、Kazuhisa Kato、Yoshihito Takahata、Satoshi Ogawa

  DOI：10.1016/j.phytol.2012.12.007

  日期：2013.5

  A novel tetra-acylated cyanidin 3-sophoroside-5-glucoside was isolated from the purple-violet flowers of Moricandia arvensis (L.) DC. (Family: Brassicaceae), and determined to be cyanidin 3-O-[2-O-(2-O-(4-O-(6-O-(4-O-(beta-glucopyranosyl)-trans-caffeoyl)-beta-glucopyranosyl)-trans-caffeoyl)-beta-glucopyranosyl)-6-O-(trans-caffeoyl)-beta-glucopyranoside]-5-O-[ 6-O-(malonyl)-beta-glucopyranoside] by chemical and spectroscopic methods. (C) 2013 Phytochemical Society of Europe. Published by Elsevier B. V. All rights reserved.