[1-(1-methoxy-ethoxy)-ethoxy]-ethene | 24261-87-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [1-(1-methoxy-ethoxy)-ethoxy]-ethene
• 英文别名: Acetaldehyd-vinyl-(1-methoxyethyl)-acetal; 3,5-Dimethyl-2,4,6-trioxaoct-7-en；1-(1-Ethenoxyethoxy)-1-methoxyethane；1-(1-ethenoxyethoxy)-1-methoxyethane
• CAS: 24261-87-8
• 化学式: C₇H₁₄O₃
• 分子量: 146.186
• InChiKey: CFVYNBMSFBDBFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 paraldehyde 生成 [1-(1-methoxy-ethoxy)-ethoxy]-ethene
  参考文献：
  名称：

  Kirmse,W.; Buschhoff,M., Chemische Berichte, 1969, vol. 102, p. 1098 - 1101

  摘要：

  DOI：

文献信息

• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。
• Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20060178449A1

  公开（公告）日：2006-08-10

  An ink composition comprising a triarylsulfonium salt polymerization initiator containing at least one aryl skeleton having an electron attractive group as a substituent, a polymerizable compound, a sensitizing dye, and a colorant.

  一种墨水组合物，包括三芳基硫鎓盐聚合引发剂，其中至少有一个含有电子吸引基团的芳基骨架作为取代基，可聚合化合物，敏化染料和着色剂。
• Curable composition for optical parts
  申请人：Awaji Toshio

  公开号：US20050192373A1

  公开（公告）日：2005-09-01

  A curable composition for optical parts, including a (meth)acrylic acid ester (A) of a compound having two or more hydroxy groups in one molecule and containing no aromatic hydrocarbon structure, wherein a content of an ether structure represented by the following general formula (1): —(O—CH 2 —CHR 1 ) n —  (1) wherein n is in the range of 1 to 100 and R 1 is at least one selected from the group consisting of hydrogen, methyl, and ethyl, in the composition is 5% by weight or higher, and a content of sulfonic acid and/or a sulfonic acid ester in the composition is 100 ppm or lower in terms of sulfur atom content. This curable composition makes it possible to obtain optical parts by curing, which are transparent and hardly cause coloration, denaturation, and deterioration to light from a light source having an emission wavelength distribution extending from a short wavelength region of visible light to an ultraviolet region.

  一种用于光学部件的可治愈组合物，包括一种（甲基）丙烯酸酯（A），其为一种化合物的（甲基）丙烯酸酯，该化合物在一个分子中具有两个或更多羟基，且不含芳香族烃结构，其中以以下一般式（1）表示的醚结构的含量为5％或更高：—（O—CH2—CHR1）n—  （1），其中n在1到100的范围内，R1至少选自氢，甲基和乙基的群组，而该组合物中磺酸和/或磺酸酯的含量以硫原子含量计为100 ppm或更低。该可治愈组合物可以通过固化获得透明的光学部件，几乎不会引起着色、变性和光源从可见光的短波长区域到紫外线区域的发射波长分布的光的恶化。
• RADIATION-CURABLE POLYMERIZABLE COMPOSITION, INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, PLANOGRAPHIC PRINTING PLATE, AND METHOD FOR FORMING PLANOGRAPHIC PRINTING PLATE
  申请人：YOKOI Kazuhiro

  公开号：US20080187727A1

  公开（公告）日：2008-08-07

  The invention provides a radiation-curable polymerizable composition of the invention having (a) a hindered amine compound having no nucleophilic moiety in a molecule, (b) a photo-acid generating agent and (c) a cationic polymerizable monomer. The invention further provides an ink composition formed of the radiation-curable polymerizable composition, a method for ink jet recording having: ejecting the ink composition onto a recording medium by using an ink jet recording apparatus and irradiating the ejected ink composition so as to cure the ink composition, and a printed material obtained thereby. The invention further provides a method for forming a planographic printing plate having: ejecting the ink composition onto a hydrophilic recording medium by using an ink jet recording apparatus; and irradiating the ejected ink composition so as to cure the ink composition for forming a hydrophobic region, and a planographic printing plate obtained thereby.

  本发明提供了一种辐射可固化的聚合物组合物，其包含(a)一种分子中没有亲核基团的受阻胺化合物，(b)一种光酸发生剂和(c)一种阳离子聚合单体。本发明还提供了一种由辐射可固化的聚合物组合物形成的墨水组合物，以及一种喷墨记录方法，其包括：使用喷墨记录设备将墨水组合物喷射到记录介质上，并照射所喷射的墨水组合物以固化墨水组合物，以及通过该方法得到的印刷材料。本发明还提供了一种形成平面印刷版的方法，其包括：使用喷墨记录设备将墨水组合物喷射到亲水性记录介质上；并照射所喷射的墨水组合物以固化墨水组合物以形成疏水区域，以及通过该方法得到的平面印刷版。