α-(carbazol-9-yl)acetyl chloride | 7167-86-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: α-(carbazol-9-yl)acetyl chloride
• 英文别名: 2-(9H-carbazol-9-yl)acetyl chloride；carbazol-9-yl-acetyl chloride；N-Carbazolyl-acetylchlorid；N-Carbazolylacetylchlorid；9-Carbazolylacetyl chloride；2-carbazol-9-ylacetyl chloride
• CAS: 7167-86-4
• 化学式: C₁₄H₁₀ClNO
• 分子量: 243.692
• InChiKey: DGMIJGXFQFBZMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  22
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  α-(carbazol-9-yl)acetyl chloride 、 邻氯苯酚 在 sodium hydroxide 作用下， 以 丙酮 为溶剂， 反应 4.0h， 以78%的产率得到o-chlorophenyl-α-(carbazol-9-yl)acetate
  参考文献：
  名称：

  Shukla, Yogendra K., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1994, vol. 33, # 8, p. 799 - 802

  摘要：

  DOI：
• 作为产物：
  描述：

  ethyl 2-(9H-carbazol-9-yl)acetate 在 sodium hydroxide 、 氯化亚砜 作用下， 以 丙酮 为溶剂， 生成 α-(carbazol-9-yl)acetyl chloride
  参考文献：
  名称：

  Shukla, Yogendra K., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1994, vol. 33, # 8, p. 799 - 802

  摘要：

  DOI：

文献信息

• Influence of polyhedral oligomeric silsesquioxanes (POSS) on blue light-emitting materials for OLED
  作者：Tianfu Zhang、Jinze Wang、Manxi Zhou、Li Ma、Guangzhong Yin、Guangxin Chen、Qifang Li

  DOI：10.1016/j.tet.2013.11.082

  日期：2014.4

  By using Heck polycondensation, we have synthesized carbazole-based alt-copolymers tethered with polyhedral oligomeric silsesquioxanes (POSS), which had well-defined architectures, similar polymerization degrees and the different contents of POSS. The effect of POSS content and the length of the side chain containing FOSS on the electroluminescence properties of these polymers were investigated. POSS particles in these alt-copolymers showed excellent dispersity and prevented the interchain aggregation of polymers in film state well. Besides, POSS benefited charge balance by increasing the electron current density, which led to a higher luminance and current efficiency, as well as purer blue light-emitting. (C) 2014 Elsevier Ltd. All rights reserved.
• Shukla Yogendra K., Srivastava Savitri D., Indian J. Pharm. Sci, 56 (1994) N 1, S 30-33
  作者：Shukla Yogendra K., Srivastava Savitri D.

  DOI：——

  日期：——
• Shukla, Yogendra K., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1994, vol. 33, # 8, p. 799 - 802
  作者：Shukla, Yogendra K.

  DOI：——

  日期：——