Dimethylformamid-diphenylacetal | 6006-64-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Dimethylformamid-diphenylacetal
• 英文别名: N,N-dimethyl-1,1-diphenoxymethanamine
• CAS: 6006-64-0
• 化学式: C₁₅H₁₇NO₂
• 分子量: 243.305
• InChiKey: TZSUINDBFNWQAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Orthoameisensaeuretriphenylester 在 三氯乙酰氯 作用下， 以 乙醚 为溶剂， 生成 Dimethylformamid-diphenylacetal
  参考文献：
  名称：

  Boehme,H.; Neidlein,R., Chemische Berichte, 1962, vol. 95, p. 1859 - 1862

  摘要：

  DOI：

文献信息

• US4060606A
  申请人：——

  公开号：US4060606A

  公开（公告）日：1977-11-29
• [EN] POLYMERIZATION PROCESS FOR PRODUCTION OF POLYDISULFIDE<br/>[FR] PROCÉDÉ DE POLYMÉRISATION POUR LA PRODUCTION DE POLYDISULFURE
  申请人：UNIV AARHUS

  公开号：WO2020254638A1

  公开（公告）日：2020-12-24

  The present invention relates to the production of polymers synthesized by polymerization of monomers comprising two thiol groups. Said polymerization is performed in the presence of a diaryl or diheteroaryl disulfide to end-cap the polymer chains. The resulting end-capped polydisulfide is easily degradable once 5the end-cap has been removed to trigger the depolymerization. End-capped polydisulfide is thus for use in the manufacturing of recyclable products and application within drug delivery, where a controlled on-demand degradation of the polymer is desirable. In particular, the present invention relates to production of end-capped polymers of dithiothreitol (DTT) which display the distinctive feature of self-immolative depolymerization. Also disclosed are copolymers created from different types of monomers. An important feature of the present invention is that the polymerization may be conducted under non-solvated conditions, without the use of any extensive heating/cooling, and in ambient air.