1-(tert-butylcarbamoyl)undec-10-enyl undec-10-enoate | 1264839-07-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1-(tert-butylcarbamoyl)undec-10-enyl undec-10-enoate
• 英文别名: [1-(Tert-butylamino)-1-oxododec-11-en-2-yl] undec-10-enoate；[1-(tert-butylamino)-1-oxododec-11-en-2-yl] undec-10-enoate
• CAS: 1264839-07-7
• 化学式: C₂₇H₄₉NO₃
• 分子量: 435.691
• InChiKey: AZIVJDSRWSMDFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  31
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  10-十一烯醛 、 2-十一烯酸 、 异氰酸叔丁酯 以 四氢呋喃 为溶剂， 以59%的产率得到1-(tert-butylcarbamoyl)undec-10-enyl undec-10-enoate
  参考文献：
  名称：

  Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers

  摘要：

  Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science.

  DOI：

  10.1021/ja1113003

文献信息

• Introducing Multicomponent Reactions to Polymer Science: Passerini Reactions of Renewable Monomers
  作者：Oliver Kreye、Tommy Tóth、Michael A. R. Meier

  DOI：10.1021/ja1113003

  日期：2011.2.16

  Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science.