N-(2-cyanoethyl)-N-ethenylformamide | 40652-50-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2-cyanoethyl)-N-ethenylformamide
• CAS: 40652-50-4
• 化学式: C₆H₈N₂O
• 分子量: 124.142
• InChiKey: SUKLLFNTKONJCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  44.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2-cyanoethyl)-N-ethenylformamide 在 镍 氢气 作用下， 生成 N-Ethyl-N-(2-cyanethyl)-formamid
  参考文献：
  名称：

  Kurtz,P.; Disselnkoetter,H., Justus Liebigs Annalen der Chemie, 1972, vol. 764, p. 69 - 93

  摘要：

  DOI：
• 作为产物：
  描述：

  N-乙烯基甲酰胺 、 丙烯腈 在 potassium cyanide 作用下， 以 苯 为溶剂， 生成 N-(2-cyanoethyl)-N-ethenylformamide
  参考文献：
  名称：

  Kurtz,P.; Disselnkoetter,H., Justus Liebigs Annalen der Chemie, 1972, vol. 764, p. 69 - 93

  摘要：

  DOI：

文献信息

• [EN] POLYMERS PREPARED FROM MIXTURES OF MULTIFUNCTIONAL N-VINYLFORMAMIDE AND HYBRID REACTIVE N-VINYLFORMAMIDE CROSSLINKING MONOMER MOIETIES AND USES THEREOF<br/>[FR] POLYMÈRES PRÉPARÉS À PARTIR DE MÉLANGES DE FRAGMENTS MONOMÈRES DE RÉTICULATION N-VINYLFORMAMIDE MULTIFONCTIONNELS ET N-VINYLFORMAMIDE RÉACTIFS HYBRIDES ET LEURS UTILISATIONS
  申请人：ISP INVESTMENTS INC

  公开号：WO2011084993A1

  公开（公告）日：2011-07-14

  The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality. The invention further provides a wide variety of compositions comprising the novel crosslinked polymers.

  本发明提供了由至少一种反应性乙烯单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一种反应性乙烯单体基团和具有至少一种N-乙烯基甲酰胺功能性和至少一种其他反应性乙烯功能性的混合N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一种具有一种N-乙烯基甲酰胺功能性和至少一种其他反应性非乙烯功能性的混合反应性N-乙烯基甲酰胺单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；以及由至少一种具有一种N-乙烯基甲酰胺功能性和至少一种其他反应性非乙烯功能性的混合反应性N-乙烯基甲酰胺单体基团和具有至少一种N-乙烯基甲酰胺功能性和至少一种其他反应性乙烯功能性的混合N-乙烃基甲酰胺交联基团聚合而成的聚合物。该发明还提供了包含新型交联聚合物的各种组合物。
• N-vinylformamide derivatives, polymers formed therefrom and synthesis thereof
  申请人：——

  公开号：US20040167338A1

  公开（公告）日：2004-08-26

  A method of synthesizing a compound having the formula: 1 comprising the step of: reacting a N-vinylformamide salt having the formula 2 with a compound having the formula XRR 1 ; wherein X is Br, Cl or I, M is an alkali metal or an alkali earth metal, R 1 is a C 0 -C 25 alkylene group, a C 0 -C 25 fluroalkylene group or a C 0 -C 25 perfluoro alkylene group, R 2 is H, provided R 1 is not absent, an alkyl group, a fluroalkyl group, a perfluoroalkyl group, an aryl group, a hydroxy group, a polyether group, a heterocyclic group of 5 or 6 atoms wherein at least one of the atoms is not a carbon and is N, O, or S, —OR 3 , wherein, R 3 is an alkyl group, a fluoroalkyl group, a perfluoroalkyl group, or an aryl group, —C(O)R 4 , —C(O)OR 4 , —OC(O)R 4 , wherein R 4 is an H, an alkyl group, a fluoroalkyl group, a perfluoroalkyl group, or an aryl group, a phthalimide group or NR 5 R 5 wherein R 5 and R 5 are independently H, —C(O)R 4 , an alkyl, a fluoroalkyl group, a perfluoroalkyl group or an aryl group.

  一种合成具有公式1的化合物的方法，包括以下步骤：将具有公式2的N-乙烯基甲酰胺盐与具有公式XRR1的化合物反应；其中，X为Br、Cl或I，M为碱金属或碱土金属，R1为C0-C25烷基、C0-C25氟烷基或C0-C25全氟烷基，R2为H（如果R1不缺失），一种烷基、氟烷基、全氟烷基、芳基、羟基、聚醚基、含5或6个原子的杂环基，其中至少一个原子不是碳，而是N、O或S，—OR3，其中R3为烷基、氟烷基、全氟烷基或芳基，—C（O）R4，—C（O）OR4，—OC（O）R4，其中R4为H、烷基、氟烷基、全氟烷基或芳基，邻苯二甲酰亚胺基或NR5R5，其中R5和R5独立地为H、—C（O）R4、一种烷基、氟烷基、全氟烷基或芳基。
• POLYMERS PREPARED FROM MIXTURES OF MULTIFUNCTIONAL N-VINYLFORMAMIDE AND HYBRID REACTIVE N-VINYLFORMAMIDE CROSSLINKING MONOMER MOIETIES AND USES THEREOF
  申请人：Musa Osama M.

  公开号：US20110166308A1

  公开（公告）日：2011-07-07

  The present invention provides polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a multifunctional N-vinylformamide crosslinking moiety; polymers resulting from polymerization of at least one reactive vinyl monomer moiety and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality; polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a multifunctional N-vinylformamide crosslinking moiety; and polymers resulting from polymerization of at least one hybrid reactive N-vinylformamide monomer moiety having one N-vinylformamide functionality and at least one other reactive non-vinyl functionality and a hybrid N-vinylformamide crosslinking moiety having at least one N-vinylformamide functionality and at least one other reactive vinyl functionality. The invention further provides a wide variety of compositions comprising the novel crosslinked polymers.

  本发明提供了由至少一个反应性乙烯单体基团和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一个反应性乙烯单体基团和具有至少一个N-乙烯基甲酰胺功能和至少一个其他反应性乙烯基团的混合型N-乙烯基甲酰胺交联基团聚合而成的聚合物；由至少一个混合型反应性N-乙烯基甲酰胺单体基团（具有一个N-乙烯基甲酰胺功能和至少一个其他反应性非乙烯基团）和多功能N-乙烯基甲酰胺交联基团聚合而成的聚合物；以及由至少一个混合型反应性N-乙烯基甲酰胺单体基团（具有一个N-乙烯基甲酰胺功能和至少一个其他反应性非乙烯基团）和具有至少一个N-乙烯基甲酰胺功能和至少一个其他反应性乙烯基团的混合型N-乙烯基甲酰胺交联基团聚合而成的聚合物。此外，本发明还提供了包含新型交联聚合物的各种组合物。
• Michael adducts of n-vinylformamide and acrylic and methacrylic esters
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0683183A1

  公开（公告）日：1995-11-22

  Novel unsaturated compounds comprising the 3-(N-vinylformamido)propionates and 2-methyl-3-(N-vinylformamido)propionates are obtained by the Michael addition reaction of N-vinylformamide with an acrylic or methacrylic acid ester. These compounds are useful as monomers in free radical polymerizations, particularly as components of photocurable coatings.

  由 3-(N-乙烯基甲酰胺基)丙酸酯和 2-甲基-3-(N-乙烯基甲酰胺基)丙酸酯组成的新型不饱和化合物是通过 N-乙烯基甲酰胺与丙烯酸酯或甲基丙烯酸酯的迈克尔加成反应获得的。这些化合物可用作自由基聚合反应中的单体，特别是用作光固化涂料的成分。
• N-vinylformamide/alkyl acrylate michael adducts
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0763522A1

  公开（公告）日：1997-03-19

  Novel unsaturated compounds comprising the 3-(N-vinylformamido)propionates and 2-methyl-3-(N-vinylformamido)propionates, or the corresponding propionamides, are obtained by the Michael addition reaction of N-vinylformamide with an acrylic or methacrylic acid ester. These compounds are useful as monomers in free radical polymerizations, particularly as components of photocurable coatings.

  新型不饱和化合物包括 3-(N-乙烯基甲酰胺基)丙酸酯和 2-甲基-3-(N-乙烯基甲酰胺基)丙酸酯或相应的丙酰胺，它们是通过 N-乙烯基甲酰胺与丙烯酸酯或甲基丙烯酸酯的迈克尔加成反应获得的。这些化合物可用作自由基聚合反应中的单体，特别是用作光固化涂料的成分。