[1-³H]ethene | 3508-18-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: [1-³H]ethene
• 英文别名: <3H>-Aethylen；Monotritio-Aethylen；T(1)-Aethylen；T1-Aethylen；Aethylen-t；Tritioethene
• CAS: 3508-18-7
• 化学式: C₂H₄
• 分子量: 30.0458
• InChiKey: VGGSQFUCUMXWEO-CNRUNOGKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氟乙烯 生成 [1-³H]ethene
  参考文献：
  名称：

  KOTAKA, MASAHIRO;KOHIDA, TOMOYUKI;SATO, SHIN, Z. NATURFORSCH. B, 45,(1990) N, C. 721-722

  摘要：

  DOI：

文献信息

• Al-Dhahir, Adnan A. Karim, Journal of the Indian Chemical Society, 1982, vol. 59, # 5, p. 632 - 634
  作者：Al-Dhahir, Adnan A. Karim

  DOI：——

  日期：——
• ——
  作者：E. V. Shchukin、T. A. Kochina、E. N. Sinotova、I. S. Ignat'ev

  DOI：10.1023/a:1012339103054

  日期：——

  Gas-phase reaction of ethylsilylium ions with ethylene was studied by the radiochemical method. The reaction occurs via excited adduct C4H11Si+ which structurally is a complex of ethylsilylium cation with ethylene. The lifetime of this complex is long enough for the isotope exchange between tritium atoms of the cation and a proton of ethylene, as well as the isomerization of ethylsilylium cation to dimethylsilylium to occur. Decomposition of the complex results in predominant formation of labeled ethylene.
• Radiochemical investigation of the interaction of nucleogenic diethylgermylium ions with methyl tert-butyl ether
  作者：D. L. Myalochkin、T. A. Kochina、D. V. Vrazhnov、V. V. Avrorin、E. N. Sinotova

  DOI：10.1134/s1070363210110095

  日期：2010.11

  Radiochemical method was used in the study of the interaction of free diethylgermylium cations with methyl tert-butyl ether in the gas and condensed phases, and the mechanisms of the relevant ion-molecular reactions were proposed. The most probable pathways of the (C2H5)(2)TGe+ cation transformation into other isomeric forms are shown as a result of B3LYP calculation with cc-pVTZ basis set.
• Trifluoromethyl hypofluorite: a fluorine-donating radical scavenger
  作者：Nunyii Wang、F. S. Rowland

  DOI：10.1021/j100270a006

  日期：1985.11
• FORNARINI, S.;SPERANZA, M., TETRAHEDRON LETT., 1984, 25, N 8, 869-872
  作者：FORNARINI, S.、SPERANZA, M.

  DOI：——

  日期：——