p-n-Butoxybenzylidene-p-n-butoxyaniline | 14921-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-n-Butoxybenzylidene-p-n-butoxyaniline
• 英文别名: <4-Butoxybenzal>-4-butoxy-anilin；4-butoxy-N-(4-butoxy-benzyliden)-aniline；4-Butoxy-N-(4-butoxy-benzyliden)-anilin；4-Butyloxy-benzaldehyd-(4-butyloxy-phenylimin)；4-butoxy-N-[(4-butoxyphenyl) methylene]benzenamine；N,1-bis(4-butoxyphenyl)methanimine
• CAS: 14921-49-4
• 化学式: C₂₁H₂₇NO₂
• 分子量: 325.451
• InChiKey: OLFGDNVRUOVGEY-UHFFFAOYSA-N

物化性质

• 沸点：
  464.0±30.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  30.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  palladium acetate 、 p-n-Butoxybenzylidene-p-n-butoxyaniline 以 溶剂黄146 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  Monomeric and dimeric ortho-metallated palladium(II)-imine systems as liquid crystals

  摘要：

  Several types of ortho-palladated complexes derived from the imines HLn=p-CnH2n+1O-C6H4-CH=N-C6H4-OCnH2n+1-p (n=2, 4, 6, 8 and 10) have been prepared and their mesogenic properties studied. The types include the dinuclear complexes [Pd(mu-X)Ln](2) with X=Cl, OAc, (R)-2-Cl-propionato or (S)-2-Br-propionato, and the mononuclear complexes [Pd(acac)Ln] and [Pd(NHacac)Ln](NHacac=4-amino-3-penten-2-onate). Most of the complexes (except the acetato derivatives and some others with very short alkoxy chains) show liquid-crystal behavior. Nematic, smectic A and smectic C phases are found. Most of the derivatives with chiral carboxylates display double melting behavior.

  DOI：

  10.1016/0022-328x(95)05771-g
• 作为产物：
  描述：

  对羟基苯甲醛 在 氢氧化钾 、 乙醇 、 环己醇 作用下， 生成 p-n-Butoxybenzylidene-p-n-butoxyaniline
  参考文献：
  名称：

  Weygand; Gabler, Journal fur praktische Chemie (Leipzig 1954), 1940, vol. <2>155, p. 332,340

  摘要：

  DOI：

文献信息

• Weygand; Gabler, Journal fur praktische Chemie (Leipzig 1954), 1940, vol. <2>155, p. 332,340
  作者：Weygand、Gabler

  DOI：——

  日期：——
• Monomeric and dimeric ortho-metallated palladium(II)-imine systems as liquid crystals
  作者：Julio Buey、Pablo Espinet

  DOI：10.1016/0022-328x(95)05771-g

  日期：1996.1

  Several types of ortho-palladated complexes derived from the imines HLn=p-CnH2n+1O-C6H4-CH=N-C6H4-OCnH2n+1-p (n=2, 4, 6, 8 and 10) have been prepared and their mesogenic properties studied. The types include the dinuclear complexes [Pd(mu-X)Ln](2) with X=Cl, OAc, (R)-2-Cl-propionato or (S)-2-Br-propionato, and the mononuclear complexes [Pd(acac)Ln] and [Pd(NHacac)Ln](NHacac=4-amino-3-penten-2-onate). Most of the complexes (except the acetato derivatives and some others with very short alkoxy chains) show liquid-crystal behavior. Nematic, smectic A and smectic C phases are found. Most of the derivatives with chiral carboxylates display double melting behavior.