O-n-Tetradecylhydroxylamin | 40345-88-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: O-n-Tetradecylhydroxylamin
• 英文别名: 1-Aminooxy-tetradecan；O-tetradecyl-hydroxylamine；O-tetradecylhydroxylamine
• CAS: 40345-88-8
• 化学式: C₁₄H₃₁NO
• 分子量: 229.406
• InChiKey: DVDAUJLPYFBUHZ-UHFFFAOYSA-N

物化性质

• 沸点：
  324.6±11.0 °C(Predicted)
• 密度：
  0.850±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  16
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  O-n-Tetradecylhydroxylamin 在 氢溴酸 作用下， 生成 十四醇
  参考文献：
  名称：

  Hutchinson,M.; Stedman,G., Journal of the Chemical Society. Perkin transactions II, 1973, p. 93 - 95

  摘要：

  DOI：
• 作为产物：
  描述：

  tetradecyloxy-carbamic acid ethyl ester 生成 O-n-Tetradecylhydroxylamin
  参考文献：
  名称：

  45.氨基氧基衍生物。第二部分 N-羟基二胍的一些衍生物

  摘要：

  DOI：

  10.1039/jr9600000229

文献信息

• Dental remineralization
  申请人：Colgate-Palmolive Company

  公开号：EP0405682A1

  公开（公告）日：1991-01-02

  A method is disclosed for remineralizing demineralized portions of teeth by treatment with a non-astringent composition containing about 10-­20% xylitol, and at least one fluoride ion-providing compound in a total amount sufficient to provide about 150 ppm to about 1800 ppm of fluoride ions, with sodium fluoride providing a predominant proportion of such fluoride ions.

  本发明公开了一种方法，通过使用含有约 10-20% 木糖醇和至少一种提供氟离子的化合物的非软化剂组合物进行处理，使牙齿的脱矿部分再矿化，该组合物的总量足以提供约 150 ppm 至约 1800 ppm 的氟离子，其中氟化钠在这些氟离子中占主要比例。
• Synthesis and Fungicidal Activity of Macrolactams and Macrolactones with an Oxime Ether Side Chain
  作者：Jia-Xing Huang、Yue-Mei Jia、Xiao-Mei Liang、Wei-Juan Zhu、Jian-Jun Zhang、Yan-Hong Dong、Hui-Zu Yuan、Shu-Hua Qi、Jin-Ping Wu、Fu-Heng Chen、Dao-Quan Wang

  DOI：10.1021/jf072733+

  日期：2007.12.1

  Three series of novel macrolactams and macrolactones - 12-alkoxyimino-tetradecanlactam, 12-alkoxyiminopentadecanlactam, and 12-alkoxyiminodecanlactone derivatives (7A, 7B, and 7C) - were synthesized from corresponding 12-oxomacrolactams and 12-oxomacrolactone. Their structures were confirmed by H-1 NMR and elemental analysis. The Z and E isomers of 7A and 7B were separated, and their configurations were determined by H-1 NMR. These compounds showed fair to excellent fungicidal activities against Rhizoctonia solani Kuhn. It is interesting that the Z and E isomers of most of the compounds have quite different fungicidal activities. The fact that the compounds have a gradual increase of fungicidal activity in the order of 7A, 7C, and 7B indicated that the macrocyclic derivatives with a hydrogen-bonding acceptor (=N-O-) and a hydrogen-bonding donor (-CONH-) on the ring, and a three methylenes distance (CH2CH2CH2) between these two functional groups, exhibited the best fungicidal activity. The bioassay also showed that 7B not only has good fungicidal activity but also may have a broad spectrum of fungicidal activities.
• Oral compositions
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP0097476B1

  公开（公告）日：1989-09-13
• US4515772A
  申请人：——

  公开号：US4515772A

  公开（公告）日：1985-05-07
• US4590066A
  申请人：——

  公开号：US4590066A

  公开（公告）日：1986-05-20