4-oxaoctadec-1-ene | 102364-25-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-oxaoctadec-1-ene
• 英文别名: Allyl tetradecyl ether；Allyl myristyl ether；1-prop-2-enoxytetradecane
• CAS: 102364-25-0
• 化学式: C₁₇H₃₄O
• 分子量: 254.456
• InChiKey: CCCDYLFPKCCVTO-UHFFFAOYSA-N

物化性质

• 沸点：
  321.8±11.0 °C(Predicted)
• 密度：
  0.819±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  18
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-oxaoctadec-1-ene 在 sodium tungstate 、 三辛基甲基硫酸铵 氨甲基膦酸 、 双氧水 作用下， 以 水 、 甲苯 为溶剂， 反应 2.0h， 以75%的产率得到[(十四烷氧基)甲基]环氧乙烷
  参考文献：
  名称：

  用 30% 过氧化氢进行烯烃环氧化的无卤化物方法

  摘要：

  由钨酸钠二水合物、（氨甲基）膦酸和甲基三辛基硫酸氢铵组成的催化体系使用 30% 的过氧化氢以 50-500 的底物与催化剂摩尔比实现烯烃的环氧化。该反应在没有溶剂的情况下以高产率进行，或者在完全无卤化物的条件下加入甲苯。取代传统氯化物的亲脂性硫酸氢铵和（α-氨基烷基）膦酸对于高反应性至关重要。这种方法操作简单，环境友好，比用间氯过苯甲酸氧化更经济，允许大规模制备环氧化物。各种底物，包括末端烯烃、1,1-和1,2-二取代烯烃、环烯烃、三取代和四取代的烯烃以及烯丙醇、酯、α,β-不饱和酮和醚可以高产率环氧化。这种新反应系统的范围和局限性...

  DOI：

  10.1246/bcsj.70.905
• 作为产物：
  描述：

  十四醇 、 3-溴丙烯 在 四丁基溴化铵 sodium hydroxide 作用下， 以 正己烷 为溶剂， 反应 6.0h， 以78%的产率得到4-oxaoctadec-1-ene
  参考文献：
  名称：

  Rao, B. V. S. K.; Gangadhar, A.; Subbarao, R., Organic Preparations and Procedures International, 1991, vol. 23, # 1, p. 119 - 122

  摘要：

  DOI：

文献信息

• Silicone polymer, paste-like silicone composition, and w/o-type cosmetic
  申请人：Kose Corporation

  公开号：US05412004A1

  公开（公告）日：1995-05-02

  A silicone polymer, a paste-like silicone composition prepared by kneading the silicone polymer and a silicone oil under a shearing force, and a water-in-oil type cosmetic composition comprising the paste-like silicone composition as an oil phase component are disclosed. The silicone polymer is prepared by the addition polymerization of components comprising an organohydrogenpolysiloxane R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (1) or R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (2) and a polyoxyalkylene C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-l (A) or an organopolysiloxane R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B) the components, including (1) or (A) as an essential component. The silicone polymer can swell in silicone oils and function as a viscosity increasing agent for silicone oils.

  本发明公开了一种硅聚合物，该硅聚合物是在剪切力下揉合硅聚合物和硅油制成的类似膏状的硅复合物，并且包括该类似膏状的硅复合物作为油相组分的水-油型化妆品组合物。所述硅聚合物是由包括有机氢基聚硅氧烷R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2(1)或R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2(2)和聚氧烷烃C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h(C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-l (A)或有机聚硅氧烷R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2(B)的组分进行加成聚合而制备的，其中包括(1)或(A)作为必需组分。该硅聚合物可以在硅油中膨胀，并作为硅油的粘度增稠剂。
• Silicone polymer, paste-like composition and water-in-oil type cosmetic composition comprising the same
  申请人：KOSE CORPORATION

  公开号：EP0545002A1

  公开（公告）日：1993-06-09

  A silicone polymer, a paste-like silicone composition prepared by kneading the silicone polymer and a silicone oil under a shearing force, and a water-in-oil type cosmetic composition comprising the paste-like silicone composition as an oil phase component are disclosed. The silicone polymer is prepared by the addition polymerization of components comprising an organohydrogenpolysiloxane R¹aR²bHcSiO(4-a-b-c)/2 (1) or R¹fHgSiO(4-f-g)/2 (2) and a polyoxyalkylene CmH2m-1O(C₂H₄O)h(C₃H₆O)iCmH2m-1 (A) or an organopolysiloxane R¹jR⁴kSiO(4-j-k)/2 (B), the components including (1) or (A) as an essential component. The silicone polymer can swell in silicone oils and function as a viscosity increasing agent for silicone oils.

  本文介绍了一种硅聚合物、一种由硅聚合物和硅油在剪切力下混合制成的类似糊状的硅复合物，以及一种以该类似糊状硅复合物为油相成分的水油型化妆品配方。硅聚合物是由包括有机氢基聚硅氧烷R¹aR²bHcSiO(4-a-b-c)/2 (1)或R¹fHgSiO(4-f-g)/2 (2)和聚氧烷CmH2m-1O(C₂H₄O)h(C₃H₆O)iCmH2m-1(A)或有机聚硅氧烷R¹jR⁴kSiO(4-j-k)/2(B)的组分进行加成聚合制备而成，其中(1)或(A)是必要组分之一。硅聚合物可以在硅油中膨胀，作为硅油的增稠剂。
• Dispersing stabilizer
  申请人：The Nippon Synthetic Chemical Industry Co., Ltd.

  公开号：EP0884332A1

  公开（公告）日：1998-12-16

  A dispersing stabilizer comprising a partially hydrolyzed polyvinyl alcohol resin having a degree of hydrolysis of 65 to 85 % by mole, and containing 0.1 to 10 % by mole of an oxyalkylene group in its side chains and 0.02 to 10 % by mole of an anionic hydrophilic group in its side chains and/or terminal. The dispersing stabilizer is suitable for suspension polymerization, emulsion polymerization or postemulsification.

  一种分散稳定剂，由部分水解的聚乙烯醇树脂组成，其水解度为 65-85%（以摩尔计），侧链中含有 0.1-10%（以摩尔计）的氧烷基，侧链和/或末端含有 0.02-10%（以摩尔计）的阴离子亲水基团。分散稳定剂适用于悬浮聚合、乳液聚合或后乳化。
• HIGHLY STABLE AQUEOUS SOLUTION OF PARTIALLY SAPONIFIED VINYL ESTER RESIN
  申请人：NIPPON GOHSEI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0978538A1

  公开（公告）日：2000-02-09

  An aqueous solution of partially hydrolyzed vinyl ester resin having an excellent stability and useful particularly as a secondary agent for suspension polymerization of vinyl compounds, wherein the partially hydrolyzed vinyl ester resin has a degree of hydrolysis of at most 70 % by mole, it is contained in a concentration of at most 50 % by weight, and it satisfies the equation: ln y > 0.042x + 1.0, in which y is the cloud point (°C) of a 30 % by weight aqueous solution of the partially hydrolyzed vinyl ester resin, and x is the degree of hydrolysis (% by mole) of the partially hydrolyzed vinyl ester resin.

  一种部分水解乙烯基酯树脂的水溶液，具有优异的稳定性，尤其可用作乙烯基化 合物悬浮聚合的辅助剂，其中部分水解乙烯基酯树脂的水解度至多为 70%（摩尔）， 其含量至多为 50%（重量），且满足以下等式：ln y > 0.042x + 1.0，其中 y 是部分水解乙烯基酯树脂 30%（重量）水溶液的浊点（℃），x 是部分水解乙烯基酯树脂的水解度（%（摩尔））。
• Film for packaging chemical agents
  申请人：The Nippon Synthetic Chemical Industry Co., Ltd.

  公开号：EP1158016A2

  公开（公告）日：2001-11-28

  The present invention provides a film for packaging chemical agents, which contains an oxyalkylene unit-containing polyvinyl alcohol resin (A) and a carboxyl-containing polyvinyl alcohol resin (B), and preferably further containing a sulfo-containing polyvinyl alcohol resin (C). This film shows fine solubility in water even after a long-term packaging of an acidic chemical agent or alkaline chemical agent, and is superior in mechanical strength. Thus, the film for packaging chemical agents of the present invention is suitably used for packaging a chemical agent, such as powdered soap, synthetic detergent, agricultural chemical, antibacterial, deodorant, insecticide and the like, which is cast into water when in use.

  本发明提供了一种用于包装化学制剂的薄膜，它含有含氧烷基单元的聚乙烯醇树脂（A）和含羧基的聚乙烯醇树脂（B），最好还含有含磺基的聚乙烯醇树脂（C）。这种薄膜即使在长期包装酸性化学制剂或碱性化学制剂后，在水中的溶解性也很好，机械强度也很高。因此，本发明的化学制剂包装薄膜适用于包装化学制剂，如肥皂粉、合成洗涤剂、农用化学品、抗菌剂、除臭剂、杀虫剂等，这些化学制剂在使用时会被抛入水中。