n-heptafluoropropylethyl ketone | 356-23-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: n-heptafluoropropylethyl ketone
• 英文别名: 4,4,5,5,6,6,6-heptafluoro-hexan-3-one；4,4,5,5,6,6,6-Heptafluor-hexan-3-on；Heptafluorpropyl-ethyl-keton；4,4,5,5,6,6,6-Heptafluorohexan-3-one
• CAS: 356-23-0
• 化学式: C₆H₅F₇O
• 分子量: 226.094
• InChiKey: MWTVYHHARBNCJL-UHFFFAOYSA-N

物化性质

• 沸点：
  78 °C
• 密度：
  1.387±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  n-heptafluoropropylethyl ketone 在 硫酸 、 溴 作用下， 生成 2-bromo-4,4,5,5,6,6,6-heptafluoro-hexan-3-one
  参考文献：
  名称：

  Notes - The Preparation and Properties of Some Fluorine-Containing Epoxides

  摘要：

  DOI：

  10.1021/jo01117a623
• 作为产物：
  描述：

  ethyl magnesium iodide 、 七氟丁腈 在 乙醚 作用下， 生成 n-heptafluoropropylethyl ketone
  参考文献：
  名称：

  The Reactions of Perfluoronitriles with Grignard Reagents¹

  摘要：

  DOI：

  10.1021/ja01609a035

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 2.2.4, page 68 - 115
  作者：

  DOI：——

  日期：——
• Haszeldine, R. N., Journal of the Chemical Society
  作者：Haszeldine, R. N.

  DOI：——

  日期：——
• A model of therapeutic intervention with Indigenous Australians
  作者：David Vicary、Henry Andrews

  DOI：10.1111/j.1467-842x.2001.tb00592.x

  日期：2001.8

  Many non-Aboriginal mental health practitioners are confronted by the lack of practical information pertaining to interventions with Aboriginal clientele. Subsequently, this may have engendered uncertainty in potential therapists and counsellors due to the lack of reliable, practical and culturally appropriate information. Those non-Aboriginal mental health practitioners working in the field with Aboriginal clients do so with varying degrees of success and build upon their knowledge base through personal experience and anecdotal information. Unfortunately, this information is often not made available to others working in the field through journal publication. This Practice Note examines a model of intervention aimed at developing relationships to enhance therapeutic interventions at the individual, family and systems level. As a way of clarification, the model is described via a case study involving a psychological intervention with a remote Aboriginal community.
• The Reformatsky Reaction with Ethyl Bromofluoroacetate¹
  作者：E. T. McBee、O. R. Pierce、D. L. Christman

  DOI：10.1021/ja01611a053

  日期：1955.3
• Chlorination of Fluorine—containing Alcohols¹
  作者：E. T. McBee、O. R. Pierce、W. F. Marzluff

  DOI：10.1021/ja01103a027

  日期：1953.4