4'-(9H-carbazol-9-yl)biphenyl-2-boronic acid | 1215228-59-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 4'-(9H-carbazol-9-yl)biphenyl-2-boronic acid
• 英文别名: [2-(4-carbazol-9-ylphenyl)phenyl]boronic acid
• CAS: 1215228-59-3
• 化学式: C₂₄H₁₈BNO₂
• 分子量: 363.223
• InChiKey: CFFHBADRUSQFSK-UHFFFAOYSA-N

物化性质

• 沸点：
  556.9±60.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.13
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  邻碘溴苯 、 4'-(9H-carbazol-9-yl)biphenyl-2-boronic acid 在 palladium diacetate 、 三(邻甲基苯基)磷 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 5.0h， 以65%的产率得到9-(2"-bromo-[1,1':2',1"]terphenyl-4-yl)-9H-carbazole
  参考文献：
  名称：

  Heterocyclic Compound, and Light-Emitting Element, Light-Emitting Device, Lighting Device, and Electronic Appliance Using Heterocyclic Compound

  摘要：

  提供一种具有双极性质的新型杂环化合物是一个目标。另一个目标是提供具有高发射效率的发光元件、发光装置和电子器件。提供了由通式（G1）表示的杂环化合物、使用由通式（G1）表示的杂环化合物形成的发光元件、发光装置和电子器件。通过使用由通式（G1）表示的杂环化合物到发光元件、发光装置和电子器件中，可以使发光元件、发光装置和电子器件具有高发射效率。

  公开号：

  US20100244672A1
• 作为产物：
  描述：

  4-(9H-咔唑-9-基)苯硼酸 在 正丁基锂 、 palladium diacetate 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 水 、 甲苯 为溶剂， 反应 32.83h， 生成 4'-(9H-carbazol-9-yl)biphenyl-2-boronic acid
  参考文献：
  名称：

  JP5693692

  摘要：

  公开号：

文献信息

• Triazole Derivative, and Light-Emitting Element, Light-Emitting Device, Lighting Device, and Electronic Device Using Triazole Derivative
  申请人：Nomura Hiroko

  公开号：US20100244674A1

  公开（公告）日：2010-09-30

  An object is to provide a novel triazole derivative having a bipolar property. Another object is to provide a light-emitting element, a light-emitting device, and an electronic device each having high emission efficiency. A triazole derivative represented by a general formula (G1), a light-emitting element, a light-emitting device, and an electronic device each formed using the triazole derivative represented by the general formula (G1) are provided. By use of the triazole derivative represented by the general formula (G1) for the light-emitting element, the light-emitting device, and the electronic device, the light-emitting element, the light-emitting device, and the electronic device each having high emission efficiency can be provided.

  本发明的一个目的是提供一种具有双极性质的新型三唑衍生物。另一个目的是提供一种具有高发射效率的发光元件、发光装置和电子设备。提供了一种由通用式（G1）表示的三唑衍生物、使用该通用式（G1）表示的三唑衍生物形成的发光元件、发光装置和电子设备。通过使用通用式（G1）表示的三唑衍生物制备发光元件、发光装置和电子设备，可以提供具有高发射效率的发光元件、发光装置和电子设备。
• Organic Semiconductor Material and Light-Emitting Element, Light-Emitting Device, Lighting System, and Electronic Device Using the Same
  申请人：Seo Satoshi

  公开号：US20100060155A1

  公开（公告）日：2010-03-11

  Disclosed is a novel organic semiconductor material which has a twisted quaterphenylene skeleton as a central unit and simultaneously possesses a skeleton having an electron-transporting property and a skeleton having a hole-transporting property at the terminals of the quaterphenylene skeleton. Specifically, the organic semiconductor material has a [1,1′:2′,1″:2″,1′″]quaterphenyl-4-4′″-diyl group, and one of the terminals of the [1,1′:2′,1″:2″,1′″]quaterphenyl-4-4′″-diyl group is bonded to a skeleton having an electron-transporting property such as a benzoxazole group or an oxadiazole group. A skeleton having a hole-transporting property such as diarylamino group is introduced at the other terminal. This structure allows the formation of a compound having a bipolar property, a high molecular weight, an excellent thermal stability, a large band gap, and high triplet excitation energy.

  本发明涉及一种新型有机半导体材料，其具有扭曲的四苯乙烯骨架作为中心单元，并同时具有具有电子输运性质的骨架和在四苯乙烯骨架的末端具有孔传输性质的骨架。具体而言，该有机半导体材料具有[1,1'-: 2'，1"-：2"，1"'-]四苯基-4-4' "-二基基团，其中[1,1'-: 2'，1"-：2"，1"'-]四苯基-4-4' "-二基基团的一个端部与具有电子输运性质的骨架（例如苯并咪唑基团或噁二唑基团）结合，而在另一个末端引入具有孔传输性质的骨架，例如二芳基胺基团。该结构允许形成具有双极性、高分子量、优异的热稳定性、大带隙和高三重激发能的化合物。
• Organic semiconductor material and light-emitting element, light-emitting device, lighting system, and electronic device using the same
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US08343639B2

  公开（公告）日：2013-01-01

  Disclosed is a novel organic semiconductor material which has a twisted quaterphenylene skeleton as a central unit and simultaneously possesses a skeleton having an electron-transporting property and a skeleton having a hole-transporting property at the terminals of the quaterphenylene skeleton. Specifically, the organic semiconductor material has a [1,1′:2′,1″:2″,1′″]quaterphenyl-4-4′″-diyl group, and one of the terminals of the [1,1′:2′,1″:2″,1′″]quaterphenyl-4-4′″-diyl group is bonded to a skeleton having an electron-transporting property such as a benzoxazole group or an oxadiazole group. A skeleton having a hole-transporting property such as diarylamino group is introduced at the other terminal. This structure allows the formation of a compound having a bipolar property, a high molecular weight, an excellent thermal stability, a large band gap, and high triplet excitation energy.

  本发明公开了一种新型的有机半导体材料，其具有扭曲的四苯基乙烯骨架作为中心单元，并同时具有具有电子传输性质的骨架和具有空穴传输性质的骨架，位于四苯基乙烯骨架的末端。具体而言，该有机半导体材料具有[1,1′:2′,1″:2″,1′″]四苯基-4-4′″-二基基团，并且[1,1′:2′,1″:2″,1′″]四苯基-4-4′″-二基基团的一个末端与具有电子传输性质的骨架（如苯并噁唑基团或噁二唑基团）键合。在另一个末端引入具有空穴传输性质的骨架，如二芳基胺基团。这种结构允许形成具有双极性、高分子量、优异的热稳定性、大带隙和高三重激发能的化合物。
• JP5693692
  申请人：——

  公开号：——

  公开（公告）日：——
• Heterocyclic Compound, and Light-Emitting Element, Light-Emitting Device, Lighting Device, and Electronic Appliance Using Heterocyclic Compound
  申请人：NOMURA Hiroko

  公开号：US20100244672A1

  公开（公告）日：2010-09-30

  An object is to provide a novel heterocyclic compound having a bipolar property. Another object is to provide a light-emitting element, a light-emitting device, and an electronic appliance each having high emission efficiency. A heterocyclic compound represented by a general formula (G1), a light-emitting element, a light-emitting device, and an electronic appliance each formed using the heterocyclic compound represented by the general formula (G1) are provided. By use of the heterocyclic compound represented by the general formula (G1) to a light-emitting element, a light-emitting device, and an electronic appliance, the light-emitting element, the light-emitting device, and the electronic appliance can each have high emission efficiency.

  提供一种具有双极性质的新型杂环化合物是一个目标。另一个目标是提供具有高发射效率的发光元件、发光装置和电子器件。提供了由通式（G1）表示的杂环化合物、使用由通式（G1）表示的杂环化合物形成的发光元件、发光装置和电子器件。通过使用由通式（G1）表示的杂环化合物到发光元件、发光装置和电子器件中，可以使发光元件、发光装置和电子器件具有高发射效率。